Unconventional 2D Periodic Nanopatterns Based on Block Molecules  

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作  者:Bo Hou Wen-Bin Zhang Yu Shao 

机构地区:[1]Beijing National Laboratory for Molecular Sciences,Key Laboratory of Polymer Chemistry&Physics of Ministry of Education,Center for Soft Matter Science and Engineering,College of Chemistry and Molecular Engineering,Peking University,Beijing,100871,China

出  处:《Chinese Journal of Polymer Science》2023年第10期1508-1524,共17页高分子科学(英文版)

基  金:financially supported by the National Natural Science Foundation of China (Nos. 21925102, 21991132, 92056118 and 22101010);the financial support from the National Key R&D Program of China (No. 2018YFB0703702);Beijing National Laboratory for Molecular Sciences (No. BNLMS-CXXM-202006)

摘  要:This review summarizes the self-assembly of block molecules forming unconventional two-dimensional(2D)periodic nanopatterns.Especially,we emphasize the structural evolution from simple columnar phases to complex 2D tiling morphologies in soft materials including block copolymers,liquid crystals,giant molecules,etc.Then,the state-of-the-art nanofabrication technologies for making sophisticated nanostructures with specific functions via combining both bottom-up assembly and top-down lithography-based methods are discussed,highlighting the use of directed self-assembly processes.Finally,we provide our perspective on this area.By further increasing the complexity of block molecules and the designability of lithography,low-dimensional ordered morphologies will be particularly promising for further application in nanotechnology.

关 键 词:Two-dimensional ordered morphologies Block molecules Directed self-assembly Nanofabrication Tilings and patterns 

分 类 号:TB383.1[一般工业技术—材料科学与工程]

 

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