综合创新实验:Zn-LiFePO_(4)软包装电池的制备与性能表征  

Comprehensive Innovative Experiment:Preparation and Characterization of Flexible Packaging Zn-LiFePO_(4)Hybrid Battery

作　　者：冯凯 朱亚茹 菅金成 刘洪浩 刘珊珊 韩艳阳 崔伟 管仁贵[1] 杨昕[1] 何涛[1] FENG Kai;ZHU Ya-Ru;JIAN Jin-Cheng;LIU Hong-Hao;LIU Shan-Shan;HAN Yan-Yang;CUI Wei;GUAN Ren-Gui;YANG Xin;HE Tao(College of Chemistry&Chemical Engineering,Yantai University,Yantai 264005,China)

机构地区：[1]烟台大学化学化工学院,山东烟台264005

出　　处：《化学教育（中英文）》2023年第18期56-63,共8页Chinese Journal of Chemical Education

基　　金：烟台大学教学改革项目:“两性一度”标准下“红专并进”型创新人才培养的基础化学实验的探索与实践(2021015)。

摘　　要：以LiFePO_(4)为正极、Zn箔为负极,以Li_(2)SO_(4)+ZnSO_(4)的饱和蔗糖溶液为电解液,利用自封袋、无纺布、不锈钢网等材料组装制备了软包装电池。通过循环伏安曲线、充放电曲线、LED灯测试等方法对电池性能进行了评估。该实验可操作性强且易重复,所用材料环境友好、安全性高、价格便宜,测试仪器简单,不需要干燥间或手套箱等复杂设备,学生在普通化学实验室就可以亲身体验软包装电池的制备流程,直观感受化学能与电能之间的转化,并深入理解氧化还原反应过程及储能电池工作原理。A feasible experiment of preparing flexible packaging hybrid batteries with LiFePO_(4)as cathode material and Zn as anode material is designed.The saturated sucrose aqueous solution containing 1 mol/L Li_(2)SO_(4)+ZnSO_(4)is used as electrolyte.The stainless-steel mesh,non-woven membrane and self-sealing bag are also used.The batteries are evaluated by cyclic voltammetry curve,battery charge-discharge curve and LED lamp test.No organic solvents or toxic chemicals are required,nor is a severe drying laboratory or a glovebox.The experiment has strong operability and repeatability.The materials used are environmentally friendly,safe and cheap.This experimental design offers new routes to familiarize students with the construction and mechanism of lithium ion batteries.The real-world applications of electrochemistry are presented visually.

关 键 词：软包装电池 LiFePO_(4)正极 Zn负极 制备 表征 

分 类 号：TM912[电气工程—电力电子与电力传动]