3D打印连续碳纤维/聚醚酮酮复合材料工艺及其性能调控  

Process and performance control of 3D printed continuous carbon fiber/poly(ether ketone ketone)composites

作　　者：周子彦 范天翔 张慧颖 吴杰[1] 陈烨[1,2] 王华平 ZHOU Ziyan;FAN Tianxiang;ZHANG Huiying;WU Jie;CHEN Ye;WANG Huaping(State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering,Donghua University,Shanghai 201620,China;Engineering Research Center of Technical Textiles,Ministry of Education,Donghua University,Shanghai 201620,China)

机构地区：[1]东华大学材料科学与工程学院,纤维材料改性国家重点实验室,上海201620 [2]东华大学产业用纺织品教育部工程研究中心,上海201620

出　　处：《复合材料学报》2023年第9期5070-5084,共15页Acta Materiae Compositae Sinica

基　　金：中央高校基本科研业务费专项资金(2232022 G-06);上海市轻质结构复合材料重点实验室开放课题(2232019 A4-10)。

摘　　要：以高热性能热塑性树脂−聚醚酮酮(PEKK)为基体与连续碳纤维(CCF)进行原位浸渍3D打印,制备连续碳纤维/聚醚酮酮复合材料(CCF/PEKK),并系统研究了3D打印工艺参数中分层厚度、流量比、打印温度及成型方向对复合材料内部结构、基体结晶、表面质量及力学性能等方面的影响。通过扫描电子显微镜观察3D打印CCF/PEKK的微观结构,采用X射线衍射分析复合材料中基体的结晶性能,使用超景深显微镜观察分析3D打印CCF/PEKK的表面形貌,同时对复合材料进行弯曲性能和层间剪切性能测试。结果显示:当分层厚度为0.2 mm、流量比为85%、打印温度为395℃,并使用水平成型方向时,3D打印CCF/PEKK复合材料的综合性能最优,其中弯曲强度达302.0 MPa,层间剪切强度达24.1 MPa。CCF/PEKK的弯曲强度较3D打印纯PEKK提升194%,层间剪切强度较工艺调控前提升113%。表明在未使用任何附加优化手段的情况下,3D打印CCF/PEKK具备制造复杂结构工程零部件的潜力。High thermal performance thermoplastic,poly(ether ketone ketone)(PEKK),was used as the matrix for in-situ impregnation 3D printing with continuous carbon fiber(CCF)to prepare continuous carbon fiber/poly(ether ketone ketone)composites(CCF/PEKK).The effects of layer thickness,flow ratio,print temperature and build orientation in 3D printing process parameters on the internal structure,matrix crystallization,surface quality and mechanical properties of the composites were systematically investigated.The microstructure of 3D printed CCF/PEKK was observed by scanning electron microscopy,the crystallization properties of the matrix were analyzed by X-ray diffraction,the surface morphologies of 3D printed CCF/PEKK was observed and analyzed by ultradeep field microscopy,and the flexural properties and interlaminar shear strength of CCF/PEKK were also tested.The results shows that with the layer thickness of 0.2 mm,the flow ratio of 85%,the printing temperature of 395°C,and the build orientation of flat,the performance of 3D printed CCF/PEKK is optimal,including the flexural strength of 302.0 MPa and the interlaminar shear strength of 24.1 MPa.The flexural strength of CCF/PEKK is improved by 194%compared with 3D printed pure PEKK,and the interlaminar shear strength is improved by 113%after process optimization.It indicates that 3D printed CCF/PEKK has the potential to manufacture complex structural engineering parts without using any additional optimization.

关 键 词：3D打印 连续碳纤维 聚醚酮酮 弯曲性能 层间剪切 

分 类 号：TB332[一般工业技术—材料科学与工程]