多组分有机框架化合物的合成及表征  

Synthesis and Characterization of Multicomponent Organic Framework Compounds

作　　者：卢瑶瑶 石鋆槿 杨棋 王仲燕 于永鑫 于涛 林琳[1] LU Yao-yao;SHI Yun-jin;YANG Qi;WANG Zhong-yan;YU Yong-xin;YU Tao;LIN Lin(College of Pharmacy,Shenyang Medical College,Shenyang 110034,China;Northeast Pharm Co.,Ltd.,Shenyang 110034,China)

机构地区：[1]沈阳医学院药学院,辽宁沈阳110034 [2]东北制药股份有限公司,辽宁沈阳110034

出　　处：《化工管理》2023年第29期46-48,63,共4页Chemical Engineering Management

基　　金：沈阳医学院大学生科研立项(项目编号:20229050);沈阳医学院科学研究基金(项目编号:20201004)。

摘　　要：文章利用苯并咪唑(BiB)和氯冉酸(CA)作为配体,通过与[Cp^(*)RhCl_(2)]_(2)反应得到双核化合物[Cp^(*)_(2)Rh_(2)(μ-BiB)]Cl_(2)和[Cp^(*)_(2)Rh_(2)(μ-CA)]Cl_(2),并通过分步配位合成法,合成了一系列四核、六核的有机金属环状和三棱柱状化合物。此外,通过引入客体分子蒽和三亚苯与主体结构发生D-A作用和π-π堆积作用,分别得到了相应的主客体有机金属化合物。In this paper,the binuclear compounds [Cp^(*)_(2)Rh_(2)(μ-BiB)]Cl_(2) and [Cp^(*)_(2)Rh_(2)(μ-CA)]Cl_(2) were synthesized by using benzimidazole(BiB) and chloranilic acid(CA) as ligand by reaction with [Cp^(*)RhCl_(2)]_(2).A series of organometallic ring and three pyramid compounds with four and six nuclei have been synthesized by stepwise coordination method.In addition,by introducing the guest molecule anthracene and triphenylene into the main structure with D-A and π-π stacking,the corresponding host-guest organometallic compounds were obtained respectively.

关 键 词：自组装 半夹心结构 有机金属大环化合物 主客体化合物 

分 类 号：O61[理学—无机化学]