煤矸石基催化剂载体的制备研究  

Study on thepreparation of Coal Gangue Based Catalyst Carrier

作　　者：马小丰 姚丽菲 刘昆[3] 刘艳娟[3] 李悦[3] 刘大成[3] Ma Xiaofeng;Yao Lifei;Liu Kun;Liu Yanjuan;Li Yue;Liu Dacheng(Coal Chemical R&D Center of Kailuan Group,Hebei,Tangshan,063018,China;Hebei Provincial Technology Innovation Centre of Coal-based Materials and Chemicals,Hebei,Tangshan,063018,China;School of New Materials and Chemical Engineering,Tangshan University,Hebei,Tangshan,063000,China)

机构地区：[1]开滦煤化工研发中心,河北唐山063018 [2]河北省煤基材料与化学品技术创新中心,河北唐山063018 [3]唐山学院新材料与化学工程学院,河北唐山063000

出　　处：《陶瓷》2023年第10期85-87,116,共4页Ceramics

摘　　要：笔者以经盐酸预处理后的煤矸石为主要原料,活性炭为造孔剂,采用挤压成形法制备煤矸石基催化剂载体,确定合理的原料配比和烧结制度,研究造孔剂添加量对催化剂载体气孔率、吸水率的影响。研究结果表明:煤矸石与苏州土配比为8∶2,烧成温度为1040℃,造孔剂活性炭添加量为35%的条件下,制备出的催化剂载体气孔率达到49.2%,催化剂载体的主要矿物相为莫来石和方石英;SEM结果显示:催化剂载体内部形成了骨架结构和贯通气孔。Coal gangue based catalyst carrier was prepared by extrusion molding method,using coal gangue as the main material and active carbon as the pore former.The effects of the pore former on catalyst carrier porosity and water absorption were studied at a certain ratio of the raw materials and sintering conditions.The results showed that the highest porosity of the catalyst carrier was 49.2%,with the ratio of coal gangue and Suzhou soil of 8∶2,the sintering temperature of 1040℃,and the active carbon addition percentage of 35%.The main mineral phase was confirmed mullite and cristobalite.According to the results of SEM characterization,a skeleton structure and penetrating pores were formed inside the catalyst carrier.

关 键 词：煤矸石 催化剂载体 粘土 气孔率 显微结构 

分 类 号：TQ174.4[化学工程—陶瓷工业]