CO_(2)与环氧化物偶合反应均相催化体系的研究进展  

Research advance of homogeneous catalytic system for coupling reaction between CO_(2) with epoxides

作　　者：刘方旺 高庆平[1] 张莉[2] 步红红 张佳佳 韩艺 江津河 Liu Fangwang;Gao Qingping;Zhang Li;Bu Honghong;Zhang Jiajia;Han Yi;Jiang Jinhe(College of Chemical Engineering,Huanbohai Green Chemical Application Technology Collaborative Innovation Center,Weifang Vocational College,Weifang,262737;College of Chemical Engineering,Weifang Key Laboratory of High-Salinity Industrial Wastewater Resource Utilization,Weifang Vocational College,Weifang,262737;College of Chemical Engineering and Environmental Engineering,Weifang University,Weifang,261061)

机构地区：[1]潍坊职业学院化学工程学院环渤海绿色化工应用技术协同创新中心,潍坊262737 [2]潍坊职业学院化学工程学院、潍坊市高盐工业废水资源化重点实验室,潍坊262737 [3]潍坊学院化学化工与环境工程学院,潍坊261061

出　　处：《化学通报》2023年第10期1188-1198,共11页Chemistry

基　　金：国家自然科学基金项目(51541205);潍坊市科学技术发展计划项目(2021GX016,2022GX020)资助。

摘　　要：二氧化碳(CO_(2))是导致全球变暖的直接原因,同时又是汇集廉价、无毒与可再生等性质的C1资源。其与环氧化物的偶合反应可展现出高的原子利用率,且产物环状碳酸酯作为一种兼具高极性、低挥发性与良好生物降解性溶剂,可普遍用于萃取剂、医药中间体和聚合物单体的制备与合成等方面。本文首先对CO_(2)与环氧化物偶合反应机理进行了分析,然后鉴于均相催化体系易制备、高活性等优点,重点从设计思路、催化参数、催化效率等方面综述了催化该偶合反应的不同均相催化体系。最后,总结了为实现均相催化体系可长久发展所必须逾越的阻碍和后续研究方向,希望能够为探索新型、高催化性能的催化体系提供参考。Carbon dioxide(CO_(2))is the main factor causing the greenhouse effect,and it is also a C1 resource with the advantage of abundant reserves,non-toxic and renewable,etc.Its coupling reaction with epoxides has high atomic economy,and the product cyclic carbonate as a solvent with high polarity,low volatility and good biodegradability,it can be widely used in the research of extractants,pharmaceutical intermediates and polymer monomers,etc.In this paper,the mechanism of coupling reaction between CO_(2) with epoxides is firstly analyzed,and in view of the advantages of homogeneous catalytic system such as easy preparation and high activity,the different homogeneous catalytic systems that catalyze the coupling reaction were systematically reviewed from the aspects of design ideas,catalytic parameters and catalytic efficiency.Finally,the obstacles that must be overcome and follow-up research direction are summarized for the sustainable development of homogeneous catalytic system,which hope to provide certain reference value for exploring new catalytic systems with high catalytic performance.

关 键 词：二氧化碳 均相催化体系 环状碳酸酯 偶合反应 

分 类 号：O621.251[理学—有机化学]