Dual photoredox and cobalt catalysis enpowers site-selective allylic amination  

作　　者：Guoqing Li Jiarong Chen 

机构地区：[1]CCNU-uOttawa Joint Research Centre,Key Laboratory of Pesticides&Chemical Biology Ministry of Education,College of Chemistry,Central China Normal University,Wuhan 430079,China

出　　处：《Green Synthesis and Catalysis》2022年第4期306-308,共3页绿色合成与催化（英文）

摘　　要：The development of a highly efficient,selective and atom-economical method for the construction of allylic amines are a challenge in green synthetic chemistry.In a recent work published in Nature Catalysis,Lei,Qi,and coworkers reported that the combination of a photoredox catalyst and cobaloxime catalyst enables site-selective allylic amination of various olefins with secondary alkyl amines,affording the valuable tertiary aliphatic allylamines,without the need for external oxidants.

关 键 词：Aliphatic allylamines Hydrogen evolution PHOTOCATALYSIS COBALOXIME Hydrogen atom transfer 

分 类 号：O62[理学—有机化学]