Two dimensional MoS_(2) finding its way towards constructing high-performance alkaline recovery membranes  

作　　者：Xinxin Li Hongwei Shao Shichao Zhang Yong Li Jingjing Gu Qiang Huang Jin Ran 

机构地区：[1]Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering,School of Chemistry and Chemical Engineering,Hefei University of Technology,Anhui 230009,China

出　　处：《Chinese Journal of Chemical Engineering》2023年第8期155-164,共10页中国化学工程学报（英文版）

基　　金：partially supported by the National Key Research and Development Program of China (2022YFB3805102);the National Natural Science Foundation of China (22278105, 21978062)。

摘　　要：The available alkaline recovery membranes are currently dominated by polymeric materials,but they suffer from a permeation-selectivity trade-off and inferior chemical resistance.Robust two dimensional(2D) lamellar membranes with sub-nanometer wide channels are promising candidates for discerning OH^(-)and other anions.Here,we report the development of alkaline recycling membranes through stacking MoS_(2) nanosheets.Benefiting from the ordered and narrow 2D channels,MoS_(2) membranes show excellent alkaline recovery performances.The OH^(-)dialysis coefficient (U_(OH)-) and separation factor (S)towards simulated OH^(-) and WO_(4)^(2-) across the 500 nm thick MoS_(2) laminates reach 6.9×10^(-3)m·h^(-1)and 34.3 respectively.Furthermore,the chemical environments of MoS_(2) laminates were modulated by intercalating ionic poly(sodium 4-styrene sulfonate)(PSS@MoS_(2)).The U_(OH)-and S values of PSS@MoS_(2) membrane further improve to 11.7×10^(-3)m·h^(-1)and 49.8 respectively.Besides,both MoS_(2) and PSS@MoS_(2) membranes exhibit promising stability.

关 键 词：Alkaline recovery Diffusion dialysis Two dimensional membranes MoS_(2) Poly(sodium 4-styrene sulfonate) 

分 类 号：TQ051.893[化学工程] X705[环境科学与工程—环境工程]