Hydrochemical evolution of groundwater in northwestern part of the Indo-Gangetic Basin,India:A geochemical and isotopic approach  

作　　者：Shive Prakash Rai Kossitse Venyo Akpataku Jacob Noble Abhinav Patel Suneel Kumar Joshi 

机构地区：[1]Department of Geology,Institute of Science,Banaras Hindu University,Varanasi 221005,India [2]Laboratory of Organic Chemistry and Environmental Sciences,Department of Chemistry,University of Kara,PO Box 404,Kara,Togo [3]Laboratory of Applied Hydrology and Environment,University of Lomé,P.O.Box 1515,Lome,Togo [4]Isotope and Radiation Application Division,Bhabha Atomic Research Centre,Mumbai 400085,India [5]Hydrological Investigations Division,National Institute of Hydrology,Roorkee 247667,India

出　　处：《Geoscience Frontiers》2023年第6期450-463,共14页地学前缘(英文版)

基　　金：supported by the Ministry of Earth Sciences,Government of India(Letter no:MoES/NERC/16/02/10 PC-II);the UK Natural Environment Research Council(grants NE/I022434/1 and NE/I022604/1);the Changing Water Cycle-South Asia program.One of the authors,Dr.Kossitse Venyo Akpataku was supported by Indian Government through DST under the RTF-DCS program(DCS/2018/000009)。

摘　　要：The present study aims to understand the hydrochemical evolution of groundwater in the Ghaggar River Basin,representing a zone of excessive abstraction of groundwater in the northwestern Indo-Gangetic Basin.The study comprises a regional scale and high-resolution sampling of groundwater during preand post-monsoon seasons of 2013 and their analyses for major ions,δ^(18)O,δ^(2)H,and 3 H.Variation in hydrochemical and isotopic data is found both in spatial and vertical scales.The significant vertical variation of TDS,NO_(3)and K^(+)allowed the classification of the aquifer system into two major groups:shallow(depth<80 m bgl)and deep(depth>80 m bgl).The depthwise variations ofδ^(18)O andδ^(2)H support this categorization of the aquifers.The Ca-HCO_(3)and Ca-Mg-Na-HCO_(3)water facies with higher values of 3 H in the proximal part of the basin characterize recharge areas under humid conditions.The dominance of Mg-Na-HCO_(3)and Na-HCO_(3)facies in shallow and deep aquifers in central part of the basin,illustrate the intermediate to advanced stages of hydrochemical evolution in the system.Dominance of brackish Ca-Mg-Cl-SO_(4)and Na-Cl-SO_(4)water types in the discharge areas is due to the prevailing geological conditions and anthropogenic activities.Geochemical modelling supports the reverse cation exchange and mixing during lateral and vertical flows,weathering of silicate minerals,dissolution of crustal salts,and evaporative enrichment are the natural processes governing the evolution of groundwater chemistry along the flowpaths.The developed process-based conceptual model will aid in the formulation of a suitable plan for groundwater resource management in the region.

关 键 词：Hydrogeochemical evolution Groundwater salinity Cation exchange FLUORIDE Anthropogenic impact Ghaggar River Basin 

分 类 号：P641.3[天文地球—地质矿产勘探] P588.145[天文地球—地质学]