基于三联吡啶配体的发光超分子组装体  

LUMINESCENT SUPRAMOLECULES BASED ON TERPYRIDINE LIGANDS

作　　者：史俊娟 魏兆彤 王明 SHI Jun-juan;WEI Zhao-tong;WANG Ming(College of Chemistry,Jilin University,Changchun,Jilin 130012,China;State Key Laboratory of Supramolecular Structure and Material,Jinlin University,Changchun,Jinlin 130012,China)

机构地区：[1]吉林大学化学学院,吉林长春130012 [2]吉林大学超分子结构与材料国家重点实验室,吉林长春130012

出　　处：《井冈山大学学报（自然科学版）》2023年第5期22-33,共12页Journal of Jinggangshan University (Natural Science)

基　　金：国家自然科学基金面上项目(22071079)。

摘　　要：发光的金属配位超分子组装体具有丰富多样的光物理特性,被广泛应用于光电材料、生物传感、催化等领域,因此,发展新型发光配位超分子结构并实现其独特发光性质一直是该领域的研究热点。本综述全面总结了基于三联吡啶的配位超分子组装体在发光领域的最新进展,围绕这些已报道的二维和三维超分子结构的构筑策略,实现材料发光性质调控的手段(浓度、压力、温度等),以及在传感、发光器件、主客体包封等方面的应用进行了总结。Emissive metal-coordinated supramolecules have been widely applied in optoelectronic materials,biosensing,catalysis and so on,due to the abundant photophysical properties.Thus,developing novel luminescent coordinated supramolecular structures and unique functions are the hot spot in this field.In this review,the recent development of supramolecular assembles based on terpyridinyl motifs was summarized comprehensively,this review evolved around the strategies of construction and function of two-and three-dimensional supramolecules,investigated means of luminescent regulation(concentration,pressure,temperature,etc.)of material luminescence to realize the tunable luminescence,and conclude the applications in sensing,light-emitting devices,host-guest encapsulation and other aspects.

关 键 词：高分子化学与物理 综述 三联吡啶 可调节发光 

分 类 号：O641.3[理学—物理化学]