Pseudorotaxane Ligand-Induced Formation of Copper(I)lodide Cluster Based Assembly Materials:From Zero to Three Dimensional  

作　　者：Xuan-Hui Zhao Na-Na Li Jun Xu Xi-Yan Dong Si Li Shuang-Quan Zang 

机构地区：[1]College of Chemistry and Chemical Engineering,Henan Polytechnic University,Jiaozuo,Henan 454000,China [2]College of Chemistry,Zhengzhou University,Zhengzhou,Henan 450001,China [3]Longbai Group Co.,Ltd.,Jiaozuo,Henan 454191,China

出　　处：《Chinese Journal of Chemistry》2023年第16期1943-1949,共7页中国化学（英文版）

基　　金：the National Natural Science Foundation of China(Nos.U21A20277,21975065,22101264,21825106);the China Postdoctoral Science Foundation(No.2021TQ0292);the Excellent Youth Foundation of Henan Scientific Committee(No.232300421022).

摘　　要：Comprehensive Summary In this work,we have successfully obtained a series of novel copper(I)–iodide clusters(CuI NCs)based assembly materials by combining supramolecular pseudorotaxane ligands{[Mebpe^(+)]PF_(6)^(–)@CB[6](CB[6]=cucurbit[6]uril),L’·PF_(6)}and linkers{BPHF@CB[6],[BPHF=C_(14)H_(20)N_(4)(PF_(6))_(2)],L·PF_(6)},including discrete cluster CuI 1 and extended cluster organic frameworks MORF 1 and MORF 2.CuI 1 can be described as a dumbbell-shaped molecule with its body-centered site and two vertexes respectively occupied by one[Cu_(5)I_(6)]^(–)cluster and two CB[6]held together by two L’·PF_(6) ligands.The crystal structures of MORF 1 and MORF 2 are 1D anionic chain and four-fold interpenetrated 3D cationic diamondoid structure,respectively,which all featured intriguing alternating CB[6]and CuI NCs.

关 键 词：Copper(Ⅰ)-iodide cluster CUCURBITURIL Supramolecular assembly Luminescence Host-guest systems Crystallization Dynamic chemistry 

分 类 号：O641.4[理学—物理化学]