Advances in Regioselective Functionalization of Endohedral Metallofullerenes  

作　　者：Yanbang Li Yue Sun William P.Kopcha Jianyuan Zhang 

机构地区：[1]Deportment of Chemistry and Chemical Biology,Rutgers,The Stote University of New Jersey,123 Bevier Rd,Piscotaway,NJ 08854,USA

出　　处：《Chinese Journal of Chemistry》2023年第16期2025-2034,共10页中国化学（英文版）

基　　金：the support of the US Department of Energy(Grant No.DE-SC0020260).

摘　　要：Comprehensive Summary Endohedral metallofullerenes(EMFs)are a family of molecules with metal clusters or ions encapsulated inside a fullerene cage.Their unique structures provide a powerful interface for organic chemists to manipulate metal elements.Over a decade ago,many reactions on empty fullerenes were adopted for EMFs,resulting in a series of reactions that are well-established and reviewed in the literature.In recent years,new topics have emerged in EMF chemistry.First,new addition reactions were developed,notably some that are not based on known empty-fullerene reactions.Second,considerable progress has been made on regioselective multi-additions on EMFs.

关 键 词：Regioselectivity FULLERENES Crystal growth CYCLOADDITION Rare earth 

分 类 号：O62[理学—有机化学]