分子探针N-烯丙基盐酸盐-4-肼基-萘酰亚胺的合成及响应效果  

Synthesis and response effect of molecular probe N-allyl hydrochloride-4-hydrazine-naphthalimide

作　　者：孙红玉 盛春英 惠杰 吕惠雯 张梦杰 邓慧 盛守祥[2] SUN Hongyu;SHENG Chunying;HUI Jie;LÜHuiwen;ZHANG Mengjie;DENG Hui;SHENG Shouxiang(Huafang Engineering Technology Research Institute Limited of Binzhou,Binzhou 256617,China;Huafang Engineering Technology Research Institute Limited,Binzhou 256617,China;Ji’nan Quality Supervision Station of Quartermaster Energy Quality Supervision General Station of PLA,Ji’nan 250022,China;Key Laboratory of New Dyeing Technology in Short Process of Shandong Province,Binzhou 256617,China)

机构地区：[1]滨州华纺工程技术研究院有限公司,山东滨州256617 [2]华纺股份有限公司技术中心,山东滨州256617 [3]军需能源质量监督总站济南质量监督站,山东济南250022 [4]山东省短流程印染新技术重点实验室,山东滨州256617

出　　处：《印染助剂》2023年第10期12-17,共6页Textile Auxiliaries

基　　金：2020年山东省自然科学基金重点项目(ZR2020KE055)。

摘　　要：以萘酰亚胺为基底物质,采用缩合反应,合成了一种分子探针N-烯丙基盐酸盐-4-肼基-萘酰亚胺,该探针可以均匀分散在不同有机溶液中。通过365nm下的紫外灯荧光照片和300~600nm荧光光谱对该探针的响应性质进行表征,通过调节二甲基亚砜溶液的pH、改变甲醛溶液的添加量和改变醛的种类来考察探针的响应性能,结果发现该探针对溶液中几种典型醛类均能够产生良好的荧光响应性。A molecular probe N-allyl hydrochloride-4-hydrazine-naphthalimide was synthesized by con-densation reaction using naphthalimide as the substrate.The probe could be uniformly dispersed in different organic solutions.The response properties of the probe were characterized by UV fluorescence photos at 365 nm and fluorescence spectra at 300-600 nm.The response performance of the probe was investigated by ad-justing the pH of the dimethyl sulfoxide solution,changing the amount of formaldehyde solution added,and changing the type of aldehyde.The results showed that the probe exhibited good fluorescence response to several typical aldehydes in the solution.

关 键 词：探针 荧光 响应 醛 

分 类 号：TQ31[化学工程—高聚物工业] TB84[一般工业技术—摄影技术]