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作 者:师良 范柏江[1] 王霞[1] 李亚婷[1] 黄飞飞 戴欣洋 SHI Liang;FAN Bojiang;WANG Xia;LI Yating;HUANG Feifei;DAI Xinyang(School of Petroleum and Environmental Engineering,Yan’an University,Yan’an,Shaanxi 716000,China)
机构地区:[1]延安大学石油工程与环境工程学院,陕西延安716000
出 处:《现代地质》2023年第5期1254-1263,共10页Geoscience
基 金:国家自然科学基金项目(41702136);陕西省自然科学基金项目(2023-JC-YB-277)。
摘 要:针对鄂尔多斯盆地长9页岩元素特征的研究相对薄弱,对其沉积环境缺乏全面揭示。本研究基于能量色散X射线荧光技术,采用优化的能量配置方法进行高精度的元素组成刻画,使得元素的有效识别数量达到29个。依据长9页岩的元素组成特征,对沉积时期的古气候、古盐度、古氧化还原状态、古生产力、古水体封闭性、物源输入等沉积环境条件进行了系统化剖析。研究结果表明,长9页岩的11个主量元素,其元素平均含量达到38341.54μg/g;18个微量元素,其元素平均含量为160.12μg/g。主量元素中,Si、Al、Fe、Ca和K的含量最高;微量元素中,Ba、Rb、Sr和Zr 4种元素的含量最高。长9页岩的微量元素中,V、Cu、Th、Rb、Zr、Nb表现为相对亏损,Co、Ni、Zn、Ga、Pb、U、Y、Cr表现为微弱富集,Ba、Sr、Mo表现为一般富集,As表现为非常富集。长9页岩的沉积环境为气候偏湿润,水体为相对贫氧-弱氧的淡水水体,水体封闭性为中等封闭-弱封闭,陆源物质供给稳定和单一,初级生产力较强。The research on the element characteristics of Chang 9 shale in Erdos Basin is inadequate,and the sedimentary environment is not fully revealed.Based on energy dispersive X-ray fluorescence technology,we used the optimized energy setting method to characterize the major and trace elements,which increases the number of measured effective elements to 29.Based on the element composition characteristics of the Chang 9 shale,the sedimentary environment(incl.paleo-climate,paleo-salinity,paleo-redox state,paleo-productivity,and provenance input)is systematically analyzed.The results show that the average content of 11 major elements in Chang 9 shale is 38,341.54μg/g;the average content of 18 trace elements is 160.12μg/g.Si,Al,Fe,Ca and K have the highest contents among the major elements;Ba,Rb,Sr and Zr have the highest contents among the trace elements.For the trace elements of the Chang 9 shale,elements including V,Cu,Th,Rb,Zr and Nb are relatively depleted;elements including Co,Ni,Zn,Ga,Pb,U,Y and Cr are weakly enriched;elements including Ba,Sr and Mo are moderately enriched;arsenic is highly enriched.The sedimentary environment of Chang 9 shale has the following characteristics:humid climate,freshwater water and weakly oxidized,medium to weak closing lake,stable terrigenous materials input,and strong primary productivity.
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