可逆质子导体陶瓷电化学电池研究进展  

Research Progress on Reversible Protonic Ceramic Electrochemical Cell

作　　者：王宙 周晓亮 刘立敏 陈晗钰 钱欣源 何非凡 绳阳 蒋星洲 WANG Zhou;ZHOU Xiaoliang;LIU Limin;CHEN Hanyu;QIAN Xinyuan;HE Feifan;SHENG Yang;JIANG Xingzhou(College of Chemistry and Chemical Engineering,Southwest Petroleum University,Chengdu 610500,China;Tianfu Yongxing Laboratory,Chengdu 610042,China)

机构地区：[1]西南石油大学化学化工学院,成都610500 [2]天府永兴实验室,成都610042

出　　处：《硅酸盐学报》2023年第10期2689-2699,共11页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金面上项目(22075231,21875056);“氢能技术”国家重点研发计划(2021YFB4001502);四川省重点研发项目(省院省校科技合作)(2020YFSY0026,2021YFSY0022);天府实验室碳中和科技创新基地建设(2021ZYD0099)。

摘　　要：可逆质子导体陶瓷电化学电池(R-PCEC)是一种既能够将化学能转化为电能,又能将电能转化为化学能的新兴高效能源转换装置。R-PCEC在燃料电池和电解电池双重模式下的可逆操作具有高度灵活性,是能量高效转换和存储最有发展前途的方式之一。然而,对于R-PCEC而言,其在实际操作条件下,电解质电导率,阴阳极的催化活性、耐久性是制约其性能的主要因素。为了对目前国内外R-PCEC技术发展现状形成全面的认识,本文详细介绍了R-PCEC各组成部分的研发现状,包括电解质材料、氢电极和空气电极的研究进展,重点阐述了可逆电池空气电极的材料要求、电极性能和反应机理等最新进展,最后对R-PCEC的发展前景进行了分析和展望。Reversible protonic ceramic electrochemical cell(R-PCEC)is an emerging and efficient energy conversion device that can convert chemical energy into electrical energy and electrical energy into chemical energy.The reversible operation of R-PCEC in the dual mode of fuel cell and electrolytic cell is highly flexible and is one of the most promising ways for efficient energy conversion and storage.However,for R-PCEC,the electrolyte conductivity,catalytic activity of the cathode and anode,and durability under actual operating conditions are the main factors restricting its performance.This review introduced the research and development status of each component of R-PCEC in detail,including electrolyte materials,hydrogen electrodes,and air electrodes,as well as mainly focused on the latest progress on material requirements,electrode performance and reaction mechanism of air electrodes for reversible batteries.In addition,the future developments on R-PCEC were also prospected.

关 键 词：可再生资源 电化学储能 高温可逆电池 质子导体 空气电极 

分 类 号：TM911[电气工程—电力电子与电力传动]