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作 者:徐绍祥 郑胜骜 黄鹏鸣 乔钰杰 刘娟 朱美华[1] 陈祥树[1] XU Shaoxiang;ZHENG Shengao;HUANG Pengming;QIAO Yujie;LIU Juan;ZHU Meihua;CHEN Xiangshu(College of Chemistry and Chemical Engineering,Institute of Advanced Materials,State-Province Joint Engineering Laboratory of Zeolite Membrane Materials,Jiangxi Normal University,Nanchang Jiangxi 330022,China)
机构地区:[1]江西师范大学化学化工学院,先进材料研究院,分子筛膜材料国家地方联合工程实验室
出 处:《江西师范大学学报(自然科学版)》2023年第5期441-450,共10页Journal of Jiangxi Normal University(Natural Science Edition)
基 金:国家自然科学基金(21868012);江西省科技厅科学技术研究课题(20171BCB24005,2019ACB80003,20181ACH80003,2020BAB203011)资助项目。
摘 要:MSE分子筛是一种具有3维孔道体系的新型分子筛,拥有较大的分子筛孔道且允许大分子在孔道内扩散,近年来备受人们关注.此外,含有杂原子的MSE分子筛具有良好的催化活性,在苯酚羟基化、烯烃环氧化等反应中表现出优异的催化性能,而且在石油加工领域中拥有长远的发展前景.近年来很多课题组展开对MSE分子筛合成路线优化的研究,然而MSE分子筛的合成一直存在着合成周期长、模板剂合成复杂等一系列问题.该文主要介绍MSE型分子筛的制备以及应用现状,并展望了MSE分子筛的发展前景.MSE zeolite is a new type of zeolite with three-dimensional pore systems and large channel system,which have attracted much attention in recent.Besides,heteroatomic MSE zeolites have good catalytic activity,which exhibit excellent catalytic performance in phenol hydroxylation,olefin epoxidation,and have a long-term development prospect in the field of petroleum processing.However,there have been a series of problems in the synthesis of MSE zeolites,such as long-term synthesis time and and complex organic template.Recently,many research groups have launched research on the optimization of the synthesis route of MSE zeolite.This study mainly summarizes the preparation,application and development prospects of MSE zeolites.
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