LiF-Sn复合修饰层改性石榴石/锂金属界面  

LiF-Sn Composite Modification Layer to Modify Garnet/Lithium Metal Interface

作　　者：杨武 郑雪凡 武玉琪 汤士军 龚正良 Wu Yang;Xue-Fan Zheng;Yu-Qi Wu;Shi-Jun Tang;Zheng-Liang Gong(College of Energy,Xiamen University,Xiamen 361005,Fujian,China)

机构地区：[1]厦门大学能源学院,福建厦门361005

出　　处：《电化学（中英文）》2023年第11期1-9,共9页Journal of Electrochemistry

基　　金：国家自然科学基金项目(No.21875196和21935009);福建省引导性计划项目(No.2019H0003);厦门大学大学生创新创业训练计划项目(No.202110384606)资助。

摘　　要：锂金属和固态电解质在能量密度和安全性能上有巨大的提升潜力,被视为全固态电池的重要组成部分。具有高锂离子电导率(约10^(–3)S·cm^(–1))和高剪切模量(55 GPa)的无机石榴石型固态电解质被认为是理想的固态电解质之一,然而锂枝晶生长的问题依旧难以解决。在本文中,通过在石榴石表面蒸镀一层LiF-Sn复合修饰层,增加石榴石与锂金属的界面浸润性的同时构建了离子快速传输通道,阻挡了电子向石榴石体相的注入,有效地抑制了锂枝晶的生长。界面修饰层的存在使得界面阻抗由969Ω·cm^(2)降低至3.5Ω·cm^(2),对称电池的临界电流密度提升至1.3 mA·cm^(–2),对称电池在0.4 mA·cm^(–2)的电流密度下稳定循环200 h。The growing demands for electric vehicles and consumer electronics,as well as the expanding renewable energy storage market,have promoted extensive research on energy storage technologies with low cost,high energy density and safety.Lithium(Li)metal and solid-state electrolytes are considered as important components for next-generation batteries because of their great potential for improvements in energy density and safety performance.Inorganic garnet-type solid electrolytes with high Li-ion conductivity(about 10^(-3)S·cm^(-1))and high shear modulus(55 GPa)are considered to be ideal solid-state electrolytes,however,the issue of Li dendrite growth still obstructs their practical application.Herein,a simple and efficient strategy was developed to suppress the Li dendrite formation in the garnet solid electrolytes.A composite modification layer made of 2 nm LiF and 2 nm Sn thin layers was prepared on the surface of the Li_(6.5)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)solid electrolyte by the high vacuum evaporation.The composite modification layer combined the advantages of LiF and Sn,which effectively improves the interfacial contact between the Li metal and LLZTO electrolyte,and promotes the uniform Li plating/stripping.The LiF-Sn composite modification layer was deposited on the surface of garnet electrolyte to increase the interfacial wettability between the garnet electrolyte and Li metal,which blocks the injection of electrons into the bulk phase of garnet.The LiF-Sn modification layer effectively enhanced the interfacial contact and inhibited the growth of lithium dendrites.Benefiting from the LiF-Sn interfacial modification,the cross-sectional SEM image shows the intimate contact between the LLZTO-LiF-Sn and the Li metal without any voids.In addition,the interfacial impedance of Li/garnet electrolyte interface decreased from 969Ω·cm^(2)to 3.5Ω·cm^(2).Meanwhile,the critical current density of the Li symmetric cell increased to 1.3 mA·cm^(-2),and the Li symmetric cell could be cycled stably for 200 h at a curr

关 键 词：LIF SN 真空热蒸镀 临界电流密度 长循环性能 

分 类 号：TB34[一般工业技术—材料科学与工程] TM912[电气工程—电力电子与电力传动]