喹喔啉-2(1H)-酮的非均相光催化C-H反应研究进展  

Progress on the Non-homogeneous Photocatalytic C-H Reaction of Quinoxalin-2(1H)-ones

作　　者：杨骐鸣 雷以柱 Yang Qiming;Lei Yizhu(School of Chemistry and Materials Engineering,Liupanshui Normal University,Liupanshui 553004,China)

机构地区：[1]六盘水师范学院化学与材料工程学院,贵州六盘水553004

出　　处：《六盘水师范学院学报》2023年第5期102-110,共9页Journal of Liupanshui Normal University

基　　金：国家自然科学基金项目“无机介孔材料多孔聚合物杂化固体酸的构筑及基催化水油两相反应性能研究”(22162017);六盘水师范学院高层次人才启动基金“自由基引发硼基迁移实现烯烃的双官能团化联合TLC-生物自显影活性筛选技术”(LPSSYKYJJ202314);六盘水师范学院学科团队项目“能源化工”(LPSSY2023XKTD04)。

摘　　要：喹喔啉-2(1H)-酮类化合物在药物和材料方面有广泛的应用,通过非均相光催化反应直接进行C-H功能化对于绿色化学发展至关重要。本综述对喹喔啉-2(1H)-酮非均相光催化反应方法进行系统总结,按照催化剂的类型分类为石墨相氮化碳、共价有机框架(COF)、离子交换树脂和微球等五部分,分别讨论喹喔啉-2(1H)-酮的不同反应类型反应条件和反应底物等。通过总结已有反应类型,对存在的不足和发展方向提出建议,如非均相光催化反应构建C-B/Si/P/RF/X/Se键,丰富非均相光催化剂类型,开发不对称合成等领域等,旨在使喹喔啉-2(1H)-酮的绿色和可持续的非均相光反应方法广泛应用于材料化学和药学。Quinoxalin-2(1H)-ones have a wide range of applications in drugs and materials,and direct C-H functionalisation via heterogeneous photocatalytic reactions is essential for the development of green chemistry.In this review,the heterogeneous photocatalytic reaction methods of quinoxalin-2(1H)-ones were systematically summarised and classified into five parts according to the types of catalysts,including graphitic phase carbon nitride,covalent organic framework(COF),ion exchange resin and micro⁃spheres.The different reaction types,reaction conditions and reaction substrates of quinoxalin-2(1H)-ones were each discussed re⁃spectively.By summarising the existing reaction types,the existing shortcomings and development directions are suggested,such as the construction of C-B/Si/P/RF/X/Se bonds in heterogeneous photocatalytic reactions,the enrichment of heterogeneous photo⁃catalyst types,the development of asymmetric synthesis and other areas.A green and sustainable heterogeneous photoreaction method to enable quinoxalin-2(1H)-ones is widely used in materials chemistry and pharmaceuticals.

关 键 词：喹喔啉-2(1H)-酮 非均相光催化 C-H功能化 

分 类 号：O626[理学—有机化学]