醋酸纤维素导电纤维膜的制备及其电热性能研究  

Preparation of cellulose acetate conductive fiber membrane and its electrothermal performance

作　　者：苏毛娜 李雅芳[1,2] 夏磊 赵义侠[1] Su Maona;Li Yafang;Xia Lei;Zhao Yixia(School of Textile Science and Engineering,Tiangong University,Tianjin 300387;Institute of Smart Wearable Electronic Textiles,Tianjin 300387)

机构地区：[1]天津工业大学纺织科学与工程学院,天津300387 [2]智能可穿戴电子纺织品研究所,天津300387

出　　处：《化工新型材料》2023年第10期139-144,共6页New Chemical Materials

基　　金：天津市自然科学基金(18JCQNJC02900)。

摘　　要：以醋酸纤维素(CA)为原料制备静电纺丝纤维膜,研究其可纺性能。结果表明,在CA的质量分数为10%~12%,纺丝距离为10~15cm,纺丝电压为12.5~17.5kV,丙酮/DMAc溶剂配比为6∶3的纺丝条件下,可以获得粗细均匀,表面平滑,且直径小于700nm的CA纳米纤维。将制备的纳米纤维膜脱乙酰化处理后,利用原位聚合法制备聚吡咯/醋酸纤维(PPy/D-CA)复合导电膜,并对其电热性能进行测试,结果表明PPy/D-CA复合导电膜具有较好的电热性能。Cellulose acetate(CA)was used as raw material to prepare electrospinning fiber membrane,and its spinnability properties were investigated.The results showed that the CA nanofibers with uniform thickness,smooth surface and diameter less than 700nm could be obtained under the conditions of CA mass fraction of 10%~12%,spinning distance of 10~15cm,spinning voltage of 12.5~17.5kV and acetone/DMAc solvent ratio of 6∶3.Polypyrrole/acetic acid fiber(PPy/D-CA)composite conductive membrane was prepared by in-situ polymerization after deacetylation of the prepared nano-fiber membrane.The electrothermal performance of PPy/D-CA composite conductive membrane was tested.The results indicated that PPy/D-CA composite conductive membrane had better electrothermal performance.

关 键 词：醋酸纤维 可纺性 聚吡咯 电热性能 

分 类 号：TQ340.64[化学工程—化纤工业]