Catalytic Cracking of Polylactic Acid to Acrylic Acid  

作　　者：Yuchen Jiao Meng Wang Ding Ma 

机构地区：[1]Beijing National Laboratory for Molecular Sciences,New Cornerstone Science Laboratory,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China

出　　处：《Chinese Journal of Chemistry》2023年第17期2071-2076,共6页中国化学（英文版）

基　　金：financial support from the National Natural Science Foundation of China(22072002,21932002,21821004);China National Petroleum Corporation-Peking University Strategic Cooperation Project of Fundamental Research.D.M.acknowledges support from the Tencent Foundation through the XPLORER.PRIZE.

摘　　要：Comprehensive Summary,As a typical type of sustainable plastic,polyesters can be recycled or upcycled into value-added chemicals in a variety of methods.However,excess reagents are required for most of the depolymerization and upcycling processes,causing the emission of environmental pollutants and the waste of chemical resources.Here we demonstrate a one-pot catalytic process to directly crack polylactic acid into acrylic acid by acid catalyst with the assistance of an ionic liquid,Bu4PBr.Polylactic acid is attacked by the Br–from Bu4PBr and the H+from acid to form oligomers containing Br or acryloyl group,and these oligomers serve as intermediates to produce acrylic acid during their mutual transformation.The acrylic acid is vaporized directly from the reactor and obtained in a collector with a selectivity around 90%when polylactic acid is fully converted.This green process shows great advantages in atom economy compared to the conventional recycling/upcycling methods for polyesters,in addition.

关 键 词：Polylactic acid Acrylic acid Atom economy Upcycling lonic liquid Commodity polymers PLASTICS Green chemistry 

分 类 号：O64[理学—物理化学]