CO_(2)基全生物降解塑料的性能突破及产业化  

Performance Breakthrough and Industrialization of CO_(2)-Based Biodegradable Plastics

作　　者：黄盛 韩东梅 王拴紧 肖敏 孟跃中 HUANG Sheng;HAN Dongmei;WANG Shuanjin;XIAO Min;MENG Yuezhong(Key Laboratory of Low-Carbon Chemistry and Energy Conservation of Guangdong Province,School of Materials Science and Engineering,Sun Yat-Sen University,Guangzhou 510006,China;Key Laboratory of Low-Carbon Chemistry and Energy Conservation of Guangdong Province,School of Chemical Engineering and Technology,Sun Yat-Sen University,Guangzhou 519082,China;Institute of Chemistry,Henan Academy of Sciences,Zhengzhou 450046,China;School of Chemistry,Zhengzhou University,Zhengzhou 450001,China)

机构地区：[1]中山大学材料科学与工程学院,广东省低碳化学及过程节能重点实验室,广东广州510006 [2]中山大学化学工程与技术学院,广东省低碳化学及过程节能重点实验室,广东珠海519082 [3]河南省科学院化学研究所,河南郑州450046 [4]郑州大学化学学院,河南郑州450001

出　　处：《同济大学学报（自然科学版）》2023年第11期1663-1666,共4页Journal of Tongji University:Natural Science

基　　金：国家自然科学基金(22179149)。

摘　　要：采用全新一代的非金属催化剂,通过加入第三单体邻苯二甲酸酐及第四单体环氧环己烷进行共聚,创制了新型的无定形聚酯‒聚碳酸酯结构的二氧化碳共聚物。该共聚物具有机械性能好、玻璃化转变温度高、阻水阻氧、全生物降解、生产工艺简单、生产过程无三废、投资极小、原料成本超低等突出优点,应用场景丰富。A new generation of non-metallic catalysts was adopted by adding the third monomer phthalic anhydride and the fourth monomer epoxycyclohexane for copolymerization to created a new type of carbon dioxide copolymer with good mechanical properties,high glass transition temperature,water and oxygen resistance,full biodegradation,simple production process,no three wastes in the production process,minimal investment,ultra-low raw material cost and other outstanding advantages,whose application is promising.

关 键 词：二氧化碳利用 全生物降解塑料 碳中和技术 

分 类 号：O633.14[理学—高分子化学]