机构地区:[1]Department of Chemistry and Green-Nano Materials Research Center,Kyungpook National University,Daegu 41566,Republic of Korea [2]Department of Chemistry,Gachon University,Seongnam 1320,Republic of Korea [3]Department of Physics,Gachon University,Seongnam 13120,Republic of Korea [4]Center for Superfunctional Materials,Department of Chemistry,Ulsan National Institute of Science and Technology(UNIST),Ulsan 44919,Republic of Korea [5]Department of Chemistry,Sri Venkateswara University,Tirupati 517502,Andhra Pradesh,India [6]Department of Civil Engineering,Yeungnam University,Gyeongsan 38541,Gyeongbuk,Republic of Korea [7]Department of Bionanotechnology,Gachon University,Seongnam 13120,Republic of Korea
出 处:《Journal of Energy Chemistry》2023年第11期409-436,I0009,共29页能源化学(英文版)
基 金:supported by the National Research Foundation(NRF-2020R1C1C1012655 NRF-2020K1A3A7A09078095,and NRF2021R1A4A5030513,M.Y.);also supported by grants from the National Research Foundation of Korea(2020R1A2C1101561 and 2021M3F6A1085886,M.J.K.)。
摘 要:The development of urbanization and industrialization leads to rapid depletion of fossil fuels.Therefore,the production of fuel from renewable resources is highly desired.Electrotechnical energy conversion and storage is a benign technique with reliable output and is eco-friendly.Developing an exceptional electrochemical catalyst with tunable properties like a huge specific surface area,porous channels,and abundant active sites is critical points.Recently,Metal-organic frameworks(MOFs)and two-dimensional(2D)transition-metal carbides/nitrides(MXenes)have been extensively investigated in the field of electrochemical energy conversion and storage.However,advances in the research on MOFs are hampered by their limited structural stability and conventionally low electrical conductivity,whereas the practical electrochemical performance of MXenes is impeded by their low porosity,inadequate redox sites,and agglomeration.Consequently,researchers have been designing MOF/MXene nanoarchitectures to overcome the limitations in electrochemical energy conversion and storage.This review explores the recent advances in MOF/MXene nanoarchitectures design strategies,tailoring their properties based on the morphologies(0D,1D,2D,and 3D),and broadening their future opportunities in electrochemical energy storage(batteries,supercapacitors)and catalytic energy conversion(HER,OER,and ORR).The intercalation of MOF in between the MXene layers in the nanoarchitectures functions synergistically to address the issues associated with bare MXene and MOF in the electrochemical energy storage and conversion.This review gives a clear emphasis on the general aspects of MOF/MXene nanoarchitectures,and the future research perspectives,challenges of MOF/MXene design strategies and electrochemical applications are highlighted.
关 键 词:Metal-organicframework MXene MoF/MXene nanoarchitecture BATTERY SUPERCAPACITOR Electrochemical catalysis
分 类 号:TB383.1[一般工业技术—材料科学与工程] O641.4[理学—物理化学]
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