Pyridine-Fused Azacorannulene:Fine-Tuning of the Structure and Properties of Nitrogen-Embedded Buckybowls  

作　　者：Kimihiro Nakamura Kotaro Ochiai Ayaka Yubuta Dan He Daigo Miyajima Shingo Ito 

机构地区：[1]School of Chemistry,Chemical Engineering and Biotechnology,Nanyang Technological University,Singapore 637371 [2]Center for Emergent Matter Science,RIKEN,Wako,Saitama 351-0198,Japan [3]College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China

出　　处：《Precision Chemistry》2023年第1期29-33,共5页精准化学（英文）

摘　　要：Heteroatom-embedded buckybowl molecules provide a fundamental molecular framework that has potential applications in various research fields.However,selective introduction of heteroatoms into buckybowls is challenging,and thus,studies investigating the effect of introduced heteroatoms have been limited.Here,we report the synthesis of pyridine-fused azacorannulene molecules.The influence of nitrogen atoms introduced into the peripheral positions on the structural,electronic,and optical properties is discussed.

关 键 词：Azacorannulene Buckybowl Polycyclic Aromatic Molecule 1 3-Dipolar Cycloaddition Azomethine Ylide 

分 类 号：O62[理学—有机化学]