介质阻挡放电等离子体转化H2S-CO_(2)酸气制合成气的影响因素研究  

The influence factors of dielectric barrier discharge plasma to production of syngas derived from H2S-CO_(2)acid gas

作　　者：余康 李民 孙高攀 周鹏 谭金浪 王斌 王涛 穆晓亮 赵璐[1] 房克功[1] YU Kang;LI Min;SUN Gao-pan;ZHOU Peng;TAN Jin-lang;WANG Bin;WANG Tao;MU Xiao-liang;ZHAO Lu;FANG Ke-gong(State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001 China;University of Chinese Academy of Sciences,Beijing 100049,China;China Energy Baotou Coal Chemical Co.,Ltd.,Baotou 014060,China)

机构地区：[1]中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001 [2]中国科学院大学,北京100049 [3]国能包头煤化工有限责任公司,内蒙古包头014060

出　　处：《燃料化学学报（中英文）》2023年第12期1782-1790,共9页Journal of Fuel Chemistry and Technology

基　　金：国家自然科学基金(21978313,21603255);中国科学院山西煤炭化学研究所创新基金(SCJC-DT-2022-05);煤转化国家重点实验室自主研究课题(2020BWZ002);中国科学院青年创新促进会人才项目(2020181);国家能源集团科技创新项目(SBCCC-CO-[2021]16)资助。

摘　　要：H_(2)S和CO_(2)两种有害酸性废气常共存于煤化工、天然气化工及石油化工等重要化工生产中,造成了工业设备及管线腐蚀,必须就地进行无害化处理。采用介质阻挡放电等离子体催化实现一步转化H_(2)S-CO_(2)混合酸气制合成气,将具有强腐蚀性、毒性的H_(2)S和温室气体CO_(2)无害化,又产出合成气,完成了以废治废的酸性废气资源化再利用。研究了用于H_(2)S-CO_(2)一步转化制合成气的介质阻挡放电等离子体反应各参数对转化反应的影响,进行了不同参数的对比研究,考察并揭示了比能量密度(SEI)、放电结构、放电频率、放电间隙以及放电区域长度等与H_(2)S-CO_(2)转化制合成气反应性能的内在关联。在此基础上设计并构建了多管并联介质阻挡放电等离子体反应系统。H_(2)S and CO_(2),two harmful acid waste gases,often co-exist in important chemical production such as coal-chemical industry,natural gas chemical industry and petrochemical industry,causing corrosion of industrial equipment and pipelines,and must be treated innocuously.Co-conversion of H_(2)S-CO_(2)mixed acid gas to syngas has been carried out using dielectric barrier discharge(DBD)plasma-catalysis,which renders the highly corrosive and toxic H_(2)S and greenhouse gas CO_(2)harmless,and produces syngas.The effects of various parameters of the DBD plasma on the reaction of one-step conversion of H_(2)S-CO_(2)to syngas were studied.Moreover,a comparative study of the different parameters of DBD plasma was carried out.The intrinsic correlation between the reaction performance of syngas production via H_(2)S-CO_(2)conversion and these parameters,including specific energy input(SEI),discharge shape,discharge frequency,discharge gap and discharge length,was investigated and revealed.On this basis,a multi-tube parallel DBD plasma reaction system was designed and constructed.

关 键 词：合成气 硫化氢 二氧化碳 低温等离子体 废物处理 

分 类 号：TQ110.9[化学工程—无机化工] X701.7[环境科学与工程—环境工程]