超声微波辐射法合成苝酰胺醇酯  

Synthesis of Perylene Amide Alcohol EsterUnder Microwave Irradiation

作　　者：刘丽敏[1] 石建军[1] 刘杨[1] LIU Limin;SHI Jianjun;LIU Yang(School of Chemistry Chemical Engineering,Anhui University of Science&Technology,Huainan 232001,Anhui China)

机构地区：[1]安徽理工大学化学与工程学院,安徽淮南232001

出　　处：《吉首大学学报（自然科学版）》2023年第5期72-76,共5页Journal of Jishou University(Natural Sciences Edition)

摘　　要：采用超声微波辐射法将N-正丙基-3,4,9,10-苝四甲酸-单酸酐-单酰亚胺与卤代烷、脂肪醇合成为N-正丙基-3,4,9,10-苝四甲酸-3,4-正丁醇酯-9,10-酰亚胺.结果表明,在超声微波辐射下,N-正丙基-3,4,9,10-苝四甲酸-3,4-正丁醇酯-9,10-酰亚胺的产率为65.7%.反应时间60 min,反应温度90℃,微波辐射功率700 W,超声功率80%为该反应的最优反应条件.N-propyl-3,4,9,10-perylene terephthalic-3,4-alcohol ester-9,10-bisimide was synthesized under ultrasonic microwave radiation with N-propyl-3,4,9,10-perylene terephthalic acid and alkyl halide,aliphatic alcohol as solvent.Results showed that this reaction afforded corresponding compound with 65.7%yields.The optimized reaction condition was as follows:700 W of microwave power,60 min of reaction time,90℃of reaction temperature,and 80%of ultrasonic power.

关 键 词：N-正丙基-3 4 9 10-苝四甲酸-3 4-正丁醇酯-9 10-酰亚胺 超声微波辐射法 脂肪醇 卤代烷 

分 类 号：O625[理学—有机化学]