糠醛催化加氢制备糠醇铜系催化剂的研究进展  

Research Progress in Copper Based Catalysts of Catalytic Hydrogenation of Furfural to Furfuryl Alcohol

作　　者：刘勤 王文玉 吴金城 刘蝈蝈 王康军 LIU Qin;WANG Wen-yu;WU Jin-cheng;LIU Guo-guo;WANG Kang-jun(College of Chemical Engineering,Shenyang University of Chemical Technology,Shenyang Liaoning 110142,China)

机构地区：[1]沈阳化工大学化学工程学院,辽宁沈阳110142

出　　处：《辽宁化工》2023年第11期1656-1659,共4页Liaoning Chemical Industry

基　　金：辽宁省兴辽英才青年拔尖人才(项目编号:XLYC1907029);辽宁省自然科学基金(项目编号:2021-NLTS-12-03);辽宁省教育厅项目面上(项目编号:LJKZ0439);辽宁省教育厅青年项目(项目编号:LJKQ2021068)。

摘　　要：总结了糠醛气相和液相催化加氢制取糠醇常见的Cu系催化剂,包括单金属Cu系催化剂、Cu-Cr系催化剂和多金属Cu系催化剂,且深入考察这3类催化剂在制备方法及其催化加氢反应中的性能表现。同时分别对比了不同组分的铜系催化剂在气相催化加氢和液相催化加氢两种不同工艺中催化性能的优劣,最后提出了糠醛催化加氢制糠醇铜系催化剂优化的建议。The common Cu series catalysts for furfural hydrogenation in vapour and liquid-phases were summarized,including monomeric Cu series catalysts,Cu-Cr series catalysts and polymetallic Cu series catalysts.The preparation methods of these three kinds of catalysts and their performance in furfural catalytic hydrogenation were discussed in depth.At the same time,the advantages and disadvantages of the catalytic performance of different components of copper catalysts in the two different processes of gas-phase catalytic hydrogenation and liquid-phase catalytic hydrogenation were compared respectively.Finally,the suggestions on the optimization of furfural catalytic hydrogenation to furfuryl alcohol copper catalyst were put forward.

关 键 词：糠醛 液相催化加氢 气相催化加氢 糠醇 Cu系催化剂 

分 类 号：TQ032.41[化学工程]