层状双氢氧化物在环境修复领域中的研究进展  

Research progress on the application of layered double hydroxides in environmental remediation

作　　者：李致达 石瑶 张凤姣 娄伟 王琳玲[1] 盛安旭 吴晓晖[1] 昝飞翔 陈静[1] LI Zhida;SHI Yao;ZHANG Fengjiao;LOU Wei;WANG Linling;SHENG Anxu;WU Xiaohui;ZAN Feixiang;CHEN Jing(School of Environmental Science and Engineering,Huazhong University of Science and Technology,Wuhan 430074,Hubei,China;Hunan Provincial Engineering Research Center for Resource Recovery and Safe Disposal of Industrial Solid Waste,Hunan Heqing Environmental Technology Company Limited,Changsha 410032,Hunan,China)

机构地区：[1]华中科技大学环境科学与工程学院,湖北武汉430074 [2]湖南省工业固废资源化与安全处置工程技术研究中心,湖南省和清环境科技有限公司,湖南长沙410032

出　　处：《化工进展》2023年第11期5801-5810,共10页Chemical Industry and Engineering Progress

基　　金：国家重点研发计划重点专项(2019YFC1805202)。

摘　　要：层状双氢氧化物(layered double hydroxides,LDHs)具有优良的吸附与催化性能。作为一种近年来被环境领域密切关注的新型功能材料,LDHs被广泛应用于去除环境中的各种污染物。本文基于对过去十几年的文献与报道进行了聚类数据分析,介绍了LDHs的制备与改性方法,总结了LDHs在环境领域中的应用。基于LDHs优异的性能,针对污染场景对LDHs进行功能改性,能够实现对特定污染物的去除,解决相应的环境问题。本文详细阐述了LDHs对染料废水、畜禽养殖和制药废水中的染料、抗生素等有机污染物的吸附和降解机制,并探讨了LDHs对采选冶废水中重金属的去除机制以及富营养化水体中氮、磷的治理,展望了LDHs在农田修复和二氧化碳捕集与资源化领域中的应用。本文为LDHs在环境领域中的应用作出较全面的总结,同时指出了LDHs研究目前存在的局限与挑战,为未来研究提供方向与思路。Layered double hydroxides(LDHs)as new functional materials were widely used to remove pollutants due to their excellent adsorption and catalytic performances.In this study,the clustering data analysis over the past decade were conducted based on keyword retrievals.The preparation of LDHs as well as modification methods were introduced.The application in environment treatment and remediation was summarized.The modification of LDHs was studied to enhance the adsorption and catalytic performances of LDHs,thus increasing their adaptability and expanding their application.Specifically,the removal and degradation mechanisms of organic pollutants,including dyes and antibiotics by LDHs in dye,pharmaceutical and poultry wastewater were discussed in detail.The influence factors on the removal of heavy metals from mining and smelting wastewater by LDHs were analyzed.The treatment of nitrogen and phosphorus in eutrophic water body were summarized.In addition,the application of LDHs in farmland soil remediation and CO_(2) capture with recycling was clarified.This paper made a comprehensive summary of the application of LDHs in the field of environment,and pointed out the limitations and challenges of LDHs research,providing direction and ideas for future research.

关 键 词：层状双氢氧化物 废水治理 水体修复 土壤修复 二氧化碳捕集 

分 类 号：O611.64[理学—无机化学] X70[理学—化学]