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作 者:Zihao Liang Baokun Liang Li Gong Yonghang Yang Fengpiao Deng Xinyu Wang Yuanjun Xia Zhipeng Zhou Xin Dong Jiaxing Lu Wei Liu Zhongke Yuan Haoyuan Qi Zhikun Zheng
机构地区:[1]Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education,School of Chemistry,and State Key,Laboratory of Optoelectronic Materials and Technologies,Sun Yat-Sen University,Guangzhou,Guangdong 510275,China [2]Central Facility for Electron Microscopy,Electron Microscopy Group of Materials Science,Universitit Ulm,89081,Ulm,Germany [3]Instrumental Analysis and Research Center,Sun Yat-Sen University,Guangzhou,Guangdong 510275,China [4]The First School of Clinical Medicine,Southern Medical University,Guangzhou,Guangdong 510515,China [5]Department of Orthopedics,General Hospital of Southern Theater Command,Guangzhou,Guangdong 510010,China [6]Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory,Jieyang,Guangdong 515200,China [7]Key Laboratory of Low-Carbon Chemistry&Energy Conservation of Guangdong Province,Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education,School of Materials Science and Engineering,and State Key Laboratory of Optoelectronic Materials and Technologies,Sun Yat-sen University,Guangzhou,Guangdong 510275,China [8]School of Chemical Engineering and Light Industry,Guangdong University pf Technology,Guangzhou,Guangdong 510006,China [9]Faculty of Chemistry and Food Chemistry&Center for Advancing Electronics Dresden(cfaed),Technische Universitat Dresden,01062,Dresden,Germany
出 处:《Chinese Journal of Chemistry》2023年第19期2425-2431,共7页中国化学(英文版)
基 金:support from the National Natural Science Foundation of China(52061135103,52173296 and 51833011).
摘 要:A core feature of two-dimensional covalent organic frameworks is crystallinity, but it remains challenging to gain their thin films with high crystallinity. Here, we presented growth of thin films of two-dimensional covalent organic frameworks with an average domain size of ~2.83 μm^(2) and maximum domain size of up to ~26.19 μm^(2) using amphiphilic glycine derivatives on water surface. We envisage that this work will inspire the growth of a wide variety of organic two-dimensional materials with high crystallinity and boost their structure property investigations.
关 键 词:Covalent organic frameworks Thin polymer films SELF-ASSEMBLY Two-dimensional polymers SURFACTANTS
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