催化加氢制备低反-反异构PACM用负载型Ru催化剂研究  

Study on supported Ru catalyst for preparation of PACM containing lower trans-trans isomer by catalytic hydrogenation

作　　者：张鹏 闫江梅 朱晨浩 唐良 方礼理 刘春红 李凡 李岳锋 Zhang Peng;Yan Jiangmei;Zhu Chenhao;Tang Liang;Fang Lili;Liu Chunhong;Li Fan;Li Yuefeng(Kaili Catalyst&New Materials Co.,Ltd.,Xi’an 710201,Shaanxi,China;National&Local Joint Engineering Research Center for New Noble Metal Catalyst R&D Technology,Xi’an 710201,Shaanxi,China;Shaanxi Key Laboratory of Catalytic Materials and Technology,Xi’an 710201,Shaanxi,China;Xi’an Key Laboratory of Catalytic Materials and Technology,Xi’an 710201,Shaanxi,China)

机构地区：[1]西安凯立新材料股份有限公司,陕西西安710201 [2]新型贵金属催化剂研发技术国家地方联合工程研究中心,陕西西安710201 [3]陕西省催化材料与技术重点实验室,陕西西安710201 [4]西安市催化材料与技术重点实验室,陕西西安710201

出　　处：《工业催化》2023年第11期72-74,共3页Industrial Catalysis

摘　　要：采用浸渍法制备了不同载体负载钌催化剂,并考察其催化4,4’-二氨基二苯基甲烷(MDA)液相加氢制备反-反异构PACM性能,重点研究了第二金属助剂协同催化对催化剂综合性能的影响。结果表明,添加金属Re后催化剂活性、选择性均有明显提升,最优的Ru∶Re金属负载比例为5∶1,此时反-反异构体含量低于20%,且催化剂具有良好的稳定性。The performance of ruthenium catalysts supported by different carriers based on impregnation method in liquid hydrogenation of 4,4’-diaminodicyclohexyl methane to trans-trans isomeric PACM was investigated,and the influence of the second metal additive on the performance of catalysts was studied.The results showed that the activity and selectivity of catalysts were significantly improved after the addition of metal Re,and the optimal loading ratio of Ru∶Re is 5∶1.The content of PACM trans-trans isomer is less than 20%.The catalyst has good stability.

关 键 词：催化剂工程 MDA 钌催化剂 加氢 4 4’-二氨基二环己基甲烷 

分 类 号：TQ426.6[化学工程] O643.36[理学—物理化学]