水溶性煤基发光碳点的室温快速合成及其在Fe^(3+)离子检测中的应用  

A highly efficient,rapid,room temperature synthesis method for coal-based water-soluble fluorescent carbon dots and its use in Fe^(3+)ion detection

作　　者：程仲富[1] 吴雪岩 刘磊[1] 何龙[1] 杨祖国[1] 曹畅[1] 吕燕 郭继玺[2] CHENG Zhong-fu;WU Xue-yan;LIU Lei;HE Long;YANG Zu-guo;CAO Chang;LU Yan;GUO Ji-xi(Sinopec Northwest Oilfield Branch Company,Urumqi 830011,China;Key Laboratory of Advanced Functional Materials,Autonomous Region,Key Laboratory of Energy Materials Chemistry,Ministry of Education,College of Chemistry,Xinjiang University,Urumqi 830046,China)

机构地区：[1]中国石油化工股份有限公司西北油田分公司,新疆乌鲁木齐830011 [2]新疆大学先进功能材料自治区重点实验室,能源材料化学教育部重点实验室,化学学院,新疆乌鲁木齐830046

出　　处：《新型炭材料（中英文）》2023年第6期1104-1115,共12页New Carbon Materials

基　　金：新疆维吾尔自治区重点实验室开放课题(2023D04032);中央引导地方科技发展资金项目(ZYYD2023B12);国家自然科学基金项目(22105163,U2003307,201972123);新疆科技创新高层次领军人才项目(2022TSYCLJ0043);新疆维吾尔自治区自然科学基金(2020D01C062);新疆维吾尔自治区天山创新团队(2021D01D09,2021D01C097).

摘　　要：碳量子点具有优异的光学性质,良好的水溶性、低毒性、原料来源广、成本低、生物相容性好等诸多优点,广泛应用于发光器件、生物检测、能源存储与转换领域,但在实际应用中还存在合成过程复杂、产率低等挑战。本文以煤为原料,以甲酸和双氧水为氧化剂,在室温下可大量合成煤基发光碳点,考查了氧化剂的添加量、反应时间对煤基发光碳点的产率及反光性质的影响,结果表明煤基发光碳点产率高达54%,且具有良好的水溶性、光稳定性、耐盐性和较高的发光量子效率。制备的煤基发光碳点可用于Fe^(3+)离子的特异性检测,检测限低于600 nmol L^(-1)。该合成方法为煤的高附加值利用和设计开发煤基新材料提供了新途径。We report a method for the of coal-based fluorescent carbon dots(CDs)at room temperature using a mixture of hydro-gen peroxide(H_(2)O_(2))and formic acid(HCOOH)as the oxidant instead of concentrated HNO_(3)or H_(2)SO_(4).The CDs have an excitation dependent behavior with a high quantum yield(QY)of approximately 7.2%.The CDs are water soluble and have excellent photo-sta-bility,good resistance to salt solutions,and are insensitive to pH in a range of 2.0-12.0.The CDs were used as a very sensitive probe for the turn-off sensing of Fe^(3+)ion with a detection limit as low as 600 nmol/L and a detection range from 2 to 100μmol/L.This work provides a way for the high value-added utilization of coal.

关 键 词：煤 碳点 合成 发光 Fe3+离子检测 

分 类 号：TQ127.11[化学工程—无机化工]