B(C_(6)F_(5))_(3)催化不饱和烃的硅化反应  

B(C_(6)F_(5))_(3)-Catalyzed Silylation of Unsaturated Hydrocarbons

作　　者：冯向青 杜海峰[1,2] Feng Xiangqing;Du Haifeng(CAS Key Laboratory of Molecular Recognition and Function,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190;University of Chinese Academy of Sciences,Beijing 100049)

机构地区：[1]中国科学院化学研究所、中国科学院分子识别与功能重点实验室,北京100190 [2]中国科学院大学,北京100049

出　　处：《有机化学》2023年第10期3544-3557,共14页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21825108)资助项目。

摘　　要：有机硅化合物由于其独特的性质,在合成化学、药物化学、高分子化学和有机光电材料等领域具有广泛的应用.不饱和化合物的硅化反应是获得有机硅化合物的重要途径之一,因此引起了化学家的关注并取得了令人瞩目的进展.B(C_(6)F_(5))_(3)作为一类独特的非金属路易斯酸,近年来,其催化不饱和烃的硅化取得了重要的研究进展,详细介绍了不饱和烃的硅化反应及机理研究.Organosilicon compounds have been widely applied in synthetic chemistry,medicinal chemistry,polymer chemistry,organic photoelectric materials and other fields due to their unique properties.The silylation of unsaturated compounds represents one of the most important approaches for the synthesis of organosilicon compounds,which has attracted the intensive attention of chemists,and a great success has been achieved.As a unique non-metallic Lewis acid,B(C_(6)F_(5))_(3)-catalyzed silylation of unsaturated compounds has made a significant progress in recent years.This subject and the corresponding mechanism are demonstrated.

关 键 词：路易斯酸 硅化反应 硅氢化反应 不饱和烃 

分 类 号：O621.251[理学—有机化学]