光催化硅氢加成反应研究进展  

Progress in Photocatalytic Hydrosilylation

作　　者：刘俊 彭家建[1] 白赢[1] 厉嘉云[1] 宋姿洁 刘鹏 欧阳婷 兰慧林 Liu Jun;Peng Jiajian;Bai Ying;Li Jiayun;Song Zijie;Liu Peng;Ouyang Ting;Lan Huilin(Key Laboratory of Organosilicon Material Technology,Zhejiang Province,Key Laboratory of Organosilicon Chemistry and Material Technology,Ministry of Education,College of Material Chemistry and Chemical Engineering,Hangzhou Normal University,Hangzhou 311121)

机构地区：[1]杭州师范大学材料与化学化工学院,有机硅化学及材料技术教育部重点实验室,浙江省有机硅材料技术重点实验室,杭州311121

出　　处：《有机化学》2023年第10期3558-3568,共11页Chinese Journal of Organic Chemistry

摘　　要：有机硅产品已成为我们生活中不可或缺的一部分.催化硅氢加成反应是制备有机硅化学品和材料的重要方法,廉价而性能优异的催化剂研制和开发受到广泛关注.目前催化硅氢加成的研究还主要集中在探索新型贵金属和非贵金属配合物的催化性能,但受贵金属高成本和非贵金属配合物较低催化活性等限制,光催化作为一种环保、安全的催化方式,光催化硅氢加成反应受到重视.介绍了近年来光催化硅氢加成反应的研究进展.Organosilicon products have become an indispensable part of our lives today.Catalytic hydrosilylation reaction is one of the important methods for preparing organosilicon chemicals and materials.The research and development of inexpensive and excellent catalysts have received extensive attention.At present,the research on catalytic hydrosilylation mainly focuses on exploring the catalytic properties of new noble metal and non-precious metal complexes.However,due to the high cost of noble metals and the low catalytic activity of non-noble metal complexes,photocatalysis is an environmentally friendly and safe method.Catalytic methods and photocatalytic hydrosilylation reactions have received much attention.In this paper,the research progress of photocatalytic hydrosilylation in recent years is introduced.

关 键 词：硅氢加成 光催化 金属配合物 自由基 光引发剂 

分 类 号：O621.251[理学—有机化学]