ZrO_(2)粒径对盐助燃烧合成纳米ZrC微观结构的影响  

Effect of ZrO_(2)Particle Size on Microstructure of Nano ZrC Synthesized by Salt Assisted Combustion

作　　者：占发琦 许世鹏 张华[1] 刘枭[1] 朱敏 郑月红[1] 喇培清 ZHAN Faqi;XU Shipeng;ZHANG Hua;LIU Xiao;ZHU Min;ZHENG Yuehong;LA Peiqing(State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals,Lanzhou University of Technology,Lanzhou 730050,China;Key Laboratory of Solar Power System Engineering,Gansu Province,Jiuquan Vocational and Technical College,Jiuquan 735000,China)

机构地区：[1]兰州理工大学,省部共建有色金属先进加工与再利用国家重点实验室,兰州730050 [2]酒泉职业技术学院,甘肃省太阳能发电系统工程重点实验室,酒泉735000

出　　处：《硅酸盐通报》2023年第12期4532-4541,共10页Bulletin of the Chinese Ceramic Society

基　　金：甘肃省高校产业支撑计划(2023CYZC-29);甘肃省太阳能发电系统工程重点实验室开放课题(2022SPKL04)。

摘　　要：采用盐助燃烧合成工艺制备了纳米碳化锆(ZrC)粉体,研究了原料氧化锆(ZrO_(2))粒径对纳米ZrC粉体微观结构的影响规律和作用机制。结果表明,在ZrO_(2)-Mg-C体系中,随着ZrO_(2)原始粒径减小(200→10 nm),碳锆体系反应活性增强,ZrC中的游离碳含量逐渐减少,ZrC粉体的平均粒径随ZrO_(2)粒径的减小而减小,当加入粒径为10 nm的ZrO_(2)时,ZrC粉体的平均粒径为48 nm,且类球形形貌更加均匀。原料ZrO_(2)粒径减小,比表面积增大,提高了反应活性和渗碳速度,从而减小了反应时间、反应温度对晶粒生长的影响,获得了分布均匀的高纯纳米ZrC粉体。Nano ZrC powder was prepared by salt assisted combustion synthesis process.The effect of raw material ZrO_(2)particle size on the microstructure of nano ZrC powder and its mechanism were studied.The results show that in ZrO_(2)-Mg-C system,with the decrease of ZrO_(2)original particle size(200→10 nm),the reaction activity of carbon zirconium system increases and the free carbon content in ZrC decreases gradually.The average particle size of ZrC powder decreases with the decrease of ZrO_(2)particle size.When ZrO_(2)with particle size of 10 nm is added,the average particle size of ZrC powder is 48 nm,and the spherical like morphology tends to be more uniform.The particle size of raw material ZrO_(2)decreases and the specific surface area increases,which improve the reaction activity and carburizing speed,so as to reduce the influences of reaction time and reaction temperature on crystal growth,and obtain high-purity nano ZrC powder with uniform distribution.

关 键 词：纳米ZrC ZrO_(2)粒径 燃烧合成 盐助 反应活性 

分 类 号：TQ134[化学工程—无机化工]