From kesterite 2D nanosheets to wurtzite 1D nanorods:controllable synthesis of Cu-Zn-Sn-S and their application in electrocatalytic hydrogen evolution  

作　　者：Yu Li Shuaibing Wang Jie Chen Ouyang Lin Zhe Yin Chunhe Yang Aiwei Tang 

机构地区：[1]Key Laboratory of Luminescence and Optical Information,Ministry of Education,School of Physical Science and Engineering,Beijing Jiaotong University,Beijing 100044,China

出　　处：《Journal of Semiconductors》2023年第12期104-110,共7页半导体学报（英文版）

基　　金：partially supported by National Natural Science Foundation of China (12274021 and 62075005)。

摘　　要：As typical quarternary copper-based chalcogenides,Cu–Zn–Sn–S nanocrystals(CZTS NCs)have emerged as a newfashioned electrocatalyst in hydrogen evolution reactions(HERs).Oleylamine(OM),a reducing surfactant and solvent,plays a significant role in the assisting synthesis of CZTS NCs due to the ligand effect.Herein,we adopted a facile one-pot colloidal method for achieving the structure evolution of CZTS NCs from 2D nanosheets to 1D nanorods assisted through the continuous addition of OM.During the process,the mechanism of OM-induced morphology evolution was further discussed.When merely adding pure 1-dodecanethiol(DDT)as the solvent,the CZTS nanosheets were obtained.As OM was gradually added to the reaction,the CZTS NCs began to grow along the sides of the nanosheets and gradually shrink at the top,followed by the formation of stable nanorods.In acidic electrolytic conditions,the CZTS NCs with 1.0 OM addition display the optimal HER activity with a low overpotential of 561 m V at 10 m A/cm^(2) and a small Tafel slope of 157.6 m V/dec compared with other CZTS samples.The enhancement of HER activity could be attributed to the contribution of the synergistic effect of the diverse crystal facets to the reaction.

关 键 词：2D nanosheets 1D nanorods structure evolution Cu-Zn-Sn-S electrocatalytic hydrogen evolution 

分 类 号：TB383.1[一般工业技术—材料科学与工程] O643.36[理学—物理化学]