有机硅过氧化物的研究进展  

Advances in the study of organosilicon peroxides

作　　者：白云 田海锋[1] 郭效军[1] 唐小华[1] 查飞[1] BAI Yun;TIAN Hai-feng;GUO Xiao-jun;TANG Xiao-hua;ZHA Fei(College of Chemistry&Chemical Engineering,Northwest Normal University,Lanzhou 730070,China)

机构地区：[1]西北师范大学化学化工学院,甘肃兰州730070

出　　处：《应用化工》2023年第11期3144-3147,共4页Applied Chemical Industry

基　　金：国家自然科学基金(22268039);甘肃省青年科技基金计划项目(20JR10RA107)。

摘　　要：有机硅过氧化物由于含有—O—O—的独特分子结构,具有较好的耐高低温性能、耐老化性能、电气绝缘性、耐臭氧性及生理惰性等优点。综述了有机硅过氧化物的性质、反应机理和用途,并具体列举了几种具有代表性的有机硅过氧化物,就其合成和用途进行介绍,为今后有机硅过氧化物的持续开发提供文献支持。The unique molecular structure of organosilicon peroxides containing—O—O—makes them have excellent high and low temperature resistance,ageing resistance,electrical insulation,ozone resistance and physiological inertness.This paper reviews the properties,reaction mechanisms and applications of organosilicon peroxides,and specifically lists several representative organosilicon peroxides and introduces their syntheses and applications,so as to provide literature support for the continuous development of organosilicon peroxides in the future.

关 键 词：有机硅过氧化物 偶联机理 交联作用 硫化作用 

分 类 号：TQ072[化学工程] U214.7[交通运输工程—道路与铁道工程]