A review on hydrogen production from ammonia borane:Experimental and theoretical studies  

作　　者：Jinrong Huo Kai Zhang Haocong Wei Ling Fu Chenxu Zhao Chaozheng He Xincheng Hu 

机构地区：[1]School of Sciences,Xi'an Technological University,Xi'an 710021,China [2]Henan Engineering Center of New Energy Battery Materials,College of Chemistry and Chemical Engineering,Shangqiu Normal University,Shangqiu 476000,China [3]School of Materials Science and Chemical Engineering,Institute of Environmental and Energy Catalysis,Xi'an Technological University,Xi'an 710021,China [4]Shaanxi Key Laboratory of Optoelectronic Functional Materials and Devices,School of Materials Science and Chemical Engineering,Xi'an Technological University,Xi'an 710021,China [5]College of Resources and Environmental Engineering,Tianshui Normal University,Tianshui 741001,China

出　　处：《Chinese Chemical Letters》2023年第12期13-28,共16页中国化学快报（英文版）

基　　金：funded by the Natural Science Basic Research Program of Shaanxi(Nos.2022JQ-108 and 2022JQ-096);the National Natural Science Foundation of China(No.22104079).

摘　　要：Ammonia borane(NHsBH3,AB)is an ideal raw material of hydrogen production with higher hydrogen storage capacity.In this paper,the catalytic processes of AB dehydrogenation were described from different ways,including thermal dehydrogenation,hydrolysis,methanolysis,photocatalysis and photopiezoelectric synergy catalysis with experimental research and theoretical calculations.Catalyst models include bulk materials,two-dimensional materials,nanocluster particles and single/diatomic structures.Among them,the proportion of H2 released is different,and the reaction conditions are also different,which are suitable for different application scenarios.Through this review,we could have a preliminary comprehensive understanding of AB dehydrogenation reaction.

关 键 词：Ammonia borane Hydrogen production Dehydrogenation catalyst HYDROLYSIS METHANOLYSIS Photo-piezoelectric synergy 

分 类 号：TQ426[化学工程] TQ116.2