阴极电流密度对超高强钢锌镍镀层腐蚀及氢脆性能的影响  

The Influence of Cathodic Current Density on Corrosion Behavior and Hydrogen Embrittlement of Ultrahigh Strength Steel

作　　者：魏琪 李文 司姗姗 张笑尘 鞠玉琳 严谨 WEI Qi;LI Wen;SI Shanshan;ZHANG Xiaochen;JU Yulin;YAN Jin(Aviation Key Laboratory of Science and Technology on Advanced Surface Engineering/Science and Technology on Power Beam Process Laboratory/AVIC Manufacturing Technology Institute,Beijing 100024,China;Department of Future Steel Research/Ansteel Beijing Research Institute Co.,Ltd.,Beijing 102209,China;College of Ma-terials Science and Engineering/Jiangsu University,Zhenjiang 212013,China;Composite Testing Technology Cen-ter/AVIC Composite Co.,Ltd.,Beijing,101300,China)

机构地区：[1]中国航空制造技术研究院/先进表面工程技术航空科技重点实验室/高能束流加工技术国家级重点实验室,北京100024 [2]鞍钢集团北京研究院有限公司/未来钢铁研究院,北京102209 [3]江苏大学材料科学与工程学院,镇江江苏212013 [4]中航复合材料有限责任公司/复合材料检测技术中心,北京101300

出　　处：《材料研究与应用》2023年第6期1101-1108,共8页Materials Research and Application

基　　金：中国航空工业“舰载机超高强钢表面防腐工艺研究”(KZ521906)。

摘　　要：碱性电镀锌镍因生产过程更环保、镀层耐蚀性好等优点,已成为代镉技术的首选。但是,由于氢脆等原因,暂未应用于超高强钢A100的表面防护。采用一种碱性镀液配方,在不同阴极电流密度下对超高强钢A100表面进行电镀及钝化,同时对钝化后的镀层进行了物相、微观形貌、电化学性能、盐雾、氢脆等组织及性能进行表征。结果表明:在阴极电流密度为2—4 A∙dm^(−2)范围内,可得到单一γ相镀层,并且镍含量在12%—13%左右;当阴极电流密度为2 A∙dm^(−2)时,析氢反应进行得比高电流密度时剧烈,电镀效率较低,需要更长的电镀时间才能得到与阴极电流密度为3—4 A∙dm^(−2)时耐蚀性相近的镀层。本镀液配方制备的镀层氢脆性能好,带有镀层的试棒均通过了200 h缺口拉伸测试,且在3—4 A∙dm^(−2)阴极电流密度电镀时渗氢电流也保持在了一个较低水平。Because of the superior corrosion resistance of the Zn-Ni layers and their ecologically benign manufacture,alkaline Zn-Ni electroplating has supplanted cadmium electroplating as the favored method.Nevertheless,it has not been used to the surface protection of ultra-high-strength steel A100 yet because of hydrogen embrittlement.Here,an alkaline plating solution was used to electroplate and passivate the ultra-high strength steel A100 at varying cathode current densities.The layers'microstructures,electrochemical characteristics,resistance to salt spray,and hydrogen embrittlement were all examined.The findings indicate that a singleγphase would form under a cathode current density range of 2—4 A∙dm^(−2),and that the electroplated layer would contain 12—13 wt%nickel.Lower electroplating efficiency is the result of a more powerful hydrogen evolution process at a cathode current density of 2 A∙dm^(−2),as opposed to higher current densities.Furthermore,compared to electroplating under 3—4 A∙dm^(−2),it takes longer to generate an electroplated layer with respectable corrosion resistance under 2 A∙dm^(−2).The A100 steel has strong resistance against hydrogen embrittlement with the alkaline plating solution.The test bars with electroplated layers can pass the 200-hour notch-tensile tests,and they also maintain a comparatively low hydrogen permeation current under 3—4 A∙dm^(−2).

关 键 词：阴极电流密度 锌镍合金镀层 超高强钢 腐蚀性能 氢脆 

分 类 号：TQ153.2[化学工程—电化学工业]