二维纳米碳材料的制备及其在苯甲醇选择性氧化反应中的应用  

Preparation of two-dimensional carbon nanomaterials and their application in the selective oxidation reaction of benzyl alcohol

作　　者：陈艺全 CHEN Yi-quan(College of Chemistry,Fuzhou University,Fuzhou 350108,China)

机构地区：[1]福州大学化学学院,福建福州350108

出　　处：《化学工程师》2023年第12期1-5,10,共6页Chemical Engineer

基　　金：教育部协同育人项目(202102249018);2022年度福建省中青年教师教育科研项目(JAT220003);2023年“福州大学贵重仪器设备开放测试基金”资助项目(2023T010)。

摘　　要：本文围绕非金属纳米碳材料的制备及其在苯甲醇选择性氧化反应中的性能调控和机理开展研究。选择富含-OH的微晶纤维素(α-cellulose)为前驱体,在较低的温度(500~700℃)下热解制备了二维纳米碳材料。研究发现,该材料在90℃下实现高效的苯甲醇选择氧化,转化率和选择性分别达到92.1%和93.7%。本研究为开发高效催化剂和促进废弃物资源化利用提供了技术支持,并对碳材料在催化领域的应用具有重要的指导意义。This study focuses on the preparation of non-metallic carbon nanomaterials and their performance modulation and mechanism in the selective oxidation reaction of benzyl alcohol.α-cellulose,which is rich in hydroxyl groups,was selected as the precursor and subjected to pyrolysis at low temperatures(500-700℃)to produce two-dimensional nanocarbon materials.It was found that the catalyst exhibited excellent reactivity in the selective oxidation of benzyl alcohol,achieving a conversion rate of 92.1%and a selectivity of 93.7%at 90℃.In summary,this research findings offer technical support for the development of efficient catalysts and the promotion of waste resource utilization.Additionally,they provide valuable guidance for the application of carbon materials in the field of catalysis.

关 键 词：碳纳米片 苯甲醇选择氧化 液相催化 活性位点 

分 类 号：TQ127.1[化学工程—无机化工]