氰氟虫腙原药中水合肼的离子色谱分析  

Analysis of hydrazine hydrate in metaflumizone technical material by ion chromatography

作　　者：刘利霞 侯春青 曹同波 谷玉 LIU Lixia;HOU Chunqing;CAO Tongbo;GU Yu(Shenyang SYRICI Testing Co.,Ltd.,Shenyang 110021,China;Shandong Jingbo Agrochemical Technology Co.,Ltd.,Binzhou 256500,Shandong,China)

机构地区：[1]沈阳沈化院测试技术有限公司,沈阳110021 [2]山东京博农化科技股份有限公司,山东滨州256500

出　　处：《农药》2023年第12期886-888,900,共4页Agrochemicals

摘　　要：[目的]建立氰氟虫腙原药中相关杂质水合肼定量分析的离子色谱方法。[方法]采用离子色谱法,使用电导检测器和IonPac CS16阳离子分析柱,在30 mmol/L甲基磺酸水溶液淋洗条件下,对水合肼进行分离和测定,外标法定量。[结果]当水合肼的质量浓度在0.019~4.90 mg/L时,水合肼的相关线性系数为0.9995,方法定量限为0.2 mg/kg;方法中水合肼的平均回收率为86.00%。[结论]该方法操作简便、快捷、准确、灵敏度高,能够满足氰氟虫腙原药中水合肼的定量分析测定要求。[Aims]The aim is to establish an ion chromatography method for the quantitative analysis of related impurities hydrazine hydrate in metaflumizone technical material.[Methods]Hydrazine hydrate was separated and determined by ion chromatography,with a conductivity detector and IonPac CS16 cation analysis column,under washing conditions of 30 mmol/L methylsulfonic acid aqueous solution.The external method was used for quantification.[Results]When the concentration of hydrazine hydrate was between 0.019 and 4.90 mg/L,the correlation linear coefficient of hydrazine hydrate was 0.9995,and the quantitative limit of the method was 0.2 mg/kg.The average recovery rate of hydrazine hydrate in the method is 86.00%.[Conclusions]The method is easy,fast,accurate,and highly sensitive,which can meet the requirements for the quantitative analysis and determination of hydrazine hydrate in metaflumizone technical.

关 键 词：离子色谱 水合肼 氰氟虫腙 定量分析 

分 类 号：TQ450.7[化学工程—农药化工]