新型液体燃料5-乙氧基甲基糠醛的催化转化研究进展  

Progress in Catalytic Conversion of 5-ethoxymethylfurfural As New Liquid Fuel

作　　者：陶姣 吕学斌[1] 潘云川 于志昊 杨诗婕 崔建国 任国权 熊健[1] TAO Jiao;LYU Xuebin;PAN Yunchuan;YU Zhihao;YANG Shijie;CUI Jianguo;REN Guoquan;XIONG Jian(School of Ecology and Environment,Tibet University,Key Lab of Biodiversity and Environment on the Qinghai-Tibetan Plateau,Ministry of Education,Key Lab of Environmental Engineering and Pollution Control on the Plateau of Tibet Autonomous Region,Lhasa,Tibet Autonomous Region,850000;School of Environmental Science and Engineering,Tianjin University,Tianjin Biomass Gas Fuel Technology Engineering Center,Tianjin,300350)

机构地区：[1]西藏大学生态环境学院,青藏高原生物多样性与生态环境保护教育部重点实验室,西藏自治区高原环境工程与污染控制重点实验室,西藏拉萨850000 [2]天津大学环境科学与工程学院,天津市生物质燃气燃油技术工程中心,天津300350

出　　处：《中国造纸学报》2023年第4期146-152,共7页Transactions of China Pulp and Paper

基　　金：中央财政支持地方高校发展专项资金项目(2022年1号,2023年1号);国家自然科学基金项目(52066017);2021年西藏自治区科技计划重点研发计划项目(XZ202101ZY0011G、XZ202101ZY0012G);西藏大学人才发展激励计划——青年学者项目资助。

摘　　要：5-乙氧基甲基糠醛(5-ethoxymethylfurfural,EMF)是一种替代化石能源的潜在液体燃料,近年来EMF的合成引起了国内外科研人员的广泛关注。本文综述了EMF转化合成的生物质原料、均相和非均相催化转化体系的研究进展,对比了单相与双相溶剂的作用效果,以期为EMF的合成与生物质转化利用提供科学依据。最后,对EMF的合成策略及工业化生产进行展望。5-ethoxymethylfurfural(EMF)is a potential liquid fuel that can replace fossil fuels.In recent years,researchers at home and abroad have paid widespread attention to the synthesis of EMF.This article reviews the research status about homogeneous and heterogeneous catalytic systems for synthesizing EMF and raw materials,and compares the effects of single-phase and two-phase solvents,in order to provide scientific basis for biomass conversion of EMF.Finally,prospects for the synthesis strategy and industrial production of EMF are proposed.

关 键 词：5-乙氧基甲基糠醛 生物质 催化 溶剂 

分 类 号：TQ251.11[化学工程—有机化工]