结构可控的酯基季铵盐多功能表面活性剂的研究进展  

Recent Advances of Multifunctional Surfactants of Quaternary Ammonium Salts with Ester Structure

作　　者：宋庆业 周忻宇 王利民[1] 韩建伟 SONG Qingye;ZHOU Xinyu;WANG Limin;HAN Jianwei(East China University of Science and Technology,School of Chemistry and Molecular Engineering,Department of Fine Chemistry,Shanghai 200237,China)

机构地区：[1]华东理工大学化学与分子工程学院精细化工系,上海200237

出　　处：《化学反应工程与工艺》2023年第6期535-544,568,共11页Chemical Reaction Engineering and Technology

基　　金：中国高校产学研创新基金(2021DZ030);国家重点研发计划(2016YFA0200300)。

摘　　要：酯基季铵盐阳离子表面活性剂相比于其他季铵盐表面活性剂,具有更好的表面活性、易生物降解性、柔顺性和抗菌性。近年来酯基季铵盐得到快速的发展,成为一类绿色环保型的表面活性剂。本文从传统的多官能团(酰胺基、糖基)的酯基季铵盐表面活性剂的合成路线和性能,单一型、双子型和聚合型酯基季铵盐抗菌的机理和活性,可控释香型多功能酯基季铵盐的性能和优势3个方面综述了多功能酯基季铵盐的研究进展,并对其研究方向进行展望。酯基季铵盐表面活性剂具有功能多样性及灵活性,在日化领域有着极为广阔的应用空间。The cationic surfactants of quaternary ammonium salts(QAS)bearing ester units have excellent surface activity,biodegradability,flexibility and antibacterial properties in comparison with common QAS.In recent years,ester based quaternary ammonium salts attract much attention due to their green environmental friendly properties.In this review,the progress of multi-functional ester quaternary ammonium salts(EQAS)was summarized with three parts:1)the synthesis and properties of traditional multi-functional EQAS;2)antibacterial mechanism and activity of various EQAS such as mono-QAS,gemini-QAS and polymeric QAS;3)the properties and advantages of multi-functional EQAS with controllable release flavor.In summary,EQAS surfactants have diverse functionality due to their structural flexibility,which could be broadly applied in the formulations of daily chemicals.

关 键 词：酯基季铵盐 表面活性剂 抗菌 释香 功能助剂 

分 类 号：TQ423.12[化学工程] TQ423.2