金属有机超分子结构的研究进展  

Research Progress on Metal-organic Supramolecular Complexes

作　　者：钟婉滢 陈名钊 Zhong Wangying;Chen Mingzhao(Guangzhou University,Institute of Environmental Research at Greater Bay Area,Guangzhou 510006,China)

机构地区：[1]广州大学,大湾区环境研究院,广东广州510006

出　　处：《广东化工》2023年第24期66-69,共4页Guangdong Chemical Industry

摘　　要：金属有机超分子是一类由金属离子和有机配体通过金属-配体配位作用组成的配合物,具有较高的结构复杂性和功能多样性,并广泛应用于化学、生物学等领域。本文对金属有机超分子的研究进展进行了综述,介绍了配体结构设计、自组装方法以及特殊性质方面的研究。在结构设计介绍了目前常用于设计配体的基团,包括单吡啶、联吡啶及三联吡啶等。在自组装方法主要概述了单金属一锅法自组装、多金属自组装、多组分自组装和特殊结构分子结的自组装的最新研究。最后,本文提出了金属有机超分子结构的发展方向与展望,以期推动这一领域的发展。Metal-organic supramolecular complexes are a category of coordination compounds composed of metal ions and organic ligands via metal-ligand coordination interactions.These compounds possess high structural complexity and functional diversity,and have been widely applied in the fields of chemistry,biology,and other disciplines.This review article summarizes the recent advances in research on metal-organic supramolecular complexes,covering the development of ligand structural design,self-assembly methods,and the exploration of unique properties.The ligand structural design section includes discussion of commonly used ligand fragments,such as pyridines,bipyridines,and terpyridines.The self-assembly methods section mainly summarizes the latest research on single-metal one-pot self-assembly,multi-metal self-assembly,multi-component self-assembly,and self-assembly of molecular knots.Finally,the paper proposes future directions and prospects for research on complexes,with the aim of driving the advancement of this field.

关 键 词：自组装 非共价相互作用 三维超分子 二维超分子 含氮配体 

分 类 号：TQ[化学工程]