Synergetic bimetallic catalysts:A remarkable platform for efficient conversion of CO_(2) to high value-added chemicals  

作　　者：Jundie Hu Fengyi Yang Jiafu Qu Yahui Cai Xiaogang Yang Chang Ming Li 

机构地区：[1]School of Materials Science and Engineering,Suzhou University of Science and Technology,Suzhou 215009,Jiangsu,China [2]College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,Jiangsu,China [3]College of Materials Science and Engineering,Nanjing Forestry University,Nanjing 210037,Jiangsu,China

出　　处：《Journal of Energy Chemistry》2023年第12期162-191,I0006,共31页能源化学（英文版）

基　　金：the financial support provided by National Natural Science Foundation of China (22008163);Postgraduate Research & Practice Innovation Program of Jiangsu Province;Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment (SKLPEE-KF202309);Natural Science Research Project of Higher Education Institutions in Jiangsu Province (20KJB150042, 21KJB150038);Natural Science Foundation of Jiangsu Province (BK20231342, BK20210867)。

摘　　要：Carbon dioxide reduction reaction(CO_(2)RR) represents an efficient approach to achieving carbon neutrality and simultaneously generating clean energy.However,the strong stability of CO_(2) molecules and the diversity of products pose significant challenges.As an emerging material,bimetallic catalysts have been widely reported for their unique advantages,such as tunable electronic structures,suitable adsorption/desorption of CO_(2) and intermediates,and optimizable d-band centers of active sites through bimetallic synergy.These catalysts provide a remarkable platform for converting CO_(2) into high value-added chemicals.This review comprehensively summarizes recent research advances in bimetallic catalysts for CO_(2)RR.Firstly,the challenges associated with CO_(2)RR,including activity and selectivity are analyzed,followed by a discussion on the unique advantages of bimetallic catalysts.Next,their synthesis strategies are categorized into dual-atom site catalysts(DACs),bimetallic nanoparticles and nanoclusters,binary metal semiconductors,and layered double hydroxides(LDHs).Additionally,advanced characterization techniques of bimetallic catalysts and their applications in CO_(2)RR are thoroughly introduced.Finally,the prospects and challenges for the application of bimetallic materials are highlighted.This review aims to provide inspiration for CO_(2)RR into high-value chemicals and shed light on the research of bimetallic materials.

关 键 词：CATALYSIS Carbon dioxide BIMETALLIC Dual-atom site catalysts SYNERGY 

分 类 号：TQ426[化学工程] TQ07