离子液体改性的金属有机框架材料催化CO_(2)与环氧化物环加成反应研究进展  

Research progress on ionic liquid modified metal organic framework materials for cycloaddition of CO_(2)and epoxides

作　　者：孟令虎 张耀远 吴芹 黎汉生 MENG Ling-hu;ZHANG Yao-yuan;WU Qin;LI Han-sheng(School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,China)

机构地区：[1]北京理工大学化学与化工学院,北京100081

出　　处：《现代化工》2024年第1期29-33,共5页Modern Chemical Industry

基　　金：国家自然科学基金项目(22108013)。

摘　　要：离子液体改性的金属有机框架材料(MOFs@IL)作为一种高活性､高稳定性､易分离的新型催化剂在CO_(2)环加成反应研究中逐渐吸引人们的注意。从催化机理､合成策略､性能表现3个方面介绍了MOFs@IL材料在CO_(2)捕获及转化为环状碳酸盐领域最新研究进展,并对未来发展方向进行总结和展望。Metal organic framework material modified by ionic liquids(MOFs@IL),as a new type of catalyst with high activity,high stability and easy separation,has gradually attracted people's attention in the study of CO_(2)cycloaddition reaction.The latest research progress on the application of MOFs@IL materials in the fields of CO_(2)capture and CO_(2)to cyclic carbonates is introduced from the aspects of catalytic mechanism,synthesis strategy,and performance,and their future development directions are summarized and prospected.

关 键 词：金属有机框架材料 CO_(2)环加成反应 离子液体 催化剂 环状碳酸酯 

分 类 号：TQ203.2[化学工程—有机化工]