配位驱动组装单组分白光发光金属-有机配合物材料的研究进展  

Research progress of coordination-driven assembly of single-component white light emission metal-organic complex materials

作　　者：申婉婷 孙少轩 冯宇婷 张凤琪 鲁婷婷 杨永晟 SHEN Wanting;SUN Shaoxuan;FENG Yuting;ZHANG Fengqi;LU Tingting;YANG Yongsheng(College of Chemistry and Chemical Engineering,Shenyang Normal University,Shenyang 110034,China;Institute of Catalysis for Energy and Environment,Shenyang Normal University,Shenyang 110034,China)

机构地区：[1]沈阳师范大学化学化工学院,沈阳110034 [2]沈阳师范大学能源与环境催化研究所,沈阳110034

出　　处：《无机化学学报》2024年第1期33-53,共21页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.22105132,22302129);辽宁省教育厅科学研究经费项目(No.LJKQZ20222267);沈阳师范大学大学生创新创业训练项目(No.X202310166225)资助。

摘　　要：金属-有机配合物材料基于其结构种类多样性及发光性能可调控的特点,被广泛应用于安全防伪、信息存储、智能传感、显示装置、白光照明等领域。本综述详细介绍了单组分金属-有机配合物在白光发光领域内的研究进展。按照Au/Ag/Cu配合物、Zn/Cd配合物、Eu和Tb共掺杂Ln配合物、染料掺杂配合物、其他主族元素/过渡元素/镧系元素掺杂/多元素掺杂配合物5个类别对配合物结构特点、发光机理、白光发光组成、白光性能指标进行分析,归纳不同类别配合物白光发光材料的构筑策略,总结金属-有机配合物材料作为白光候选材料具备的优势,并从理论研究和实际应用2个方面提出待进一步解决的问题,以期早日实现金属-有机配合物发光材料的工业化生产及应用。Metal-organic complex materials are widely used in security and anti-counterfeiting,information storage,intelligent sensing,display devices,white light lighting,and other fields based on their structural diversity and controllable luminescence properties.In this review,the research progress of single-component metal-organic complexes in white light luminescence is introduced in detail.According to the five categories of Au(Ⅰ)/Ag(Ⅰ)/Cu(Ⅰ) complexes,Zn(Ⅱ)/Cd(Ⅱ) complexes,Eu(Ⅲ) &Tb(Ⅲ) co-doped Ln(Ⅲ) complexes,dye-doped complexes,other main group elements/transition elements/lanthanide elements doped/multi-element doped complexes,the structural characteristics,luminescence mechanism,white light luminescence composition and white light performance index of complexes are analyzed.The construction strategies of white light emission materials of different types of complexes are generalized.The advantages of metal-organic complex materials as white light candidate materials are summarized,and the problems to be further solved are put forward from two aspects of theoretical research and practical application,to realize the industrial production and application of metal-organic complex luminescent materials as soon as possible.

关 键 词：金属-有机配合物 单组分 结构多样性 发光可调控 白光发光 

分 类 号：O614[理学—无机化学] TB333[理学—化学]