金属有机骨架(MOFs)衍生材料及其在催化领域的研究进展  

Metal organic frameworks(MOFs)-derived materials and their recent advances in the field of catalysis

作　　者：范宜凯 邬娇娇 徐向亚[1] 白帆 白杰[1] 刘东兵[1] Fan Yikai;Wu Jiaojiao;Xu Xiangya;Bai Fan;Bai Jie;Liu Dongbing(Sinopec Beijing Research Institute of Chemical Industry,Beijing 100013,China)

机构地区：[1]中国石化北京化工研究院,北京100013

出　　处：《工业催化》2024年第1期14-19,共6页Industrial Catalysis

基　　金：中国石油化工股份有限公司北京化工研究院项目(6-21ZS0224)。

摘　　要：金属有机骨架(MOFs)材料是一类具有大比表面积和可调孔结构的新型多孔材料,近年来在催化制备精细化学品领域受到广泛关注。在实际催化过程中,MOFs较差的稳定性制约了其在许多反应中的应用。以MOFs为前驱体制备的MOFs衍生材料能够保留MOFs材料结构上的优势,同时解决其稳定性差的问题,极大拓展MOFs材料在催化反应中的应用。综述MOFs衍生材料在催化领域特别是在加氢和氧化制备精细化学品中的研究进展,并对MOF衍生材料面临的问题及其在催化领域的应用前景进行了展望。Metal organic frameworks(MOFs),a new class of porous materials with high specific surface areas and tunable pore structures,have been received growing attention for fine chemical synthesis in recent years.However,the poor stability of MOFs restricts their application in many catalytic processes.MOFs-derived materials prepared with MOFs as precursor can inherit the structural advantages of MOFs,and also overcome the stability issue of MOFs,which expands the applications of MOFs in catalytic reaction.Herein,research progresses of MOFs derived materials in catalytic field,especially in hydrogenation and oxidation for fine chemical production are reviewed.Furthermore,the existing challenges and development prospects of MOFs derived materials using in catalytic field are also discussed.

关 键 词：催化剂工程 金属有机骨架(MOFs)衍生材料 有序多孔结构 单原子催化剂 

分 类 号：TQ426.6[化学工程] TB332[一般工业技术—材料科学与工程]