双离子电池中阴离子可逆体系设计与正极材料研究进展  

Design of Anion Reversible Systems and Research Progress of Cathode Materials in Dualion Batteries

作　　者：帕提曼·阿不都 何一涛 白翔 伊尔夏提·地里夏提 罗新泽 何晓燕 闫秀玲 李海金 PATIMAN Abudu;HE Yitao;BAI Xiang;YIERXIATI Dilixiati;LUO Xinze;HE Xiaoyan;YAN Xiuling;LI Haijin(Key Laboratory of Pollutant Chemistry and Environmental Treatment,School of Chemistry and Environmental Sciences,YiLi Normal University,Yining 835000,Xinjiang,China;School of Energy and Environment,Department of Energy and Power Engineering,Anhui University of Technology,Maanshan 243002,Anhui,China)

机构地区：[1]伊犁师范大学化学与环境科学学院,污染物化学与环境治理重点实验室,新疆伊宁835000 [2]安徽工业大学能源与环境学院,能源与动力工程系,安徽马鞍山243002

出　　处：《材料导报》2024年第2期19-31,共13页Materials Reports

基　　金：国家自然科学基金青年科学基金(5220021063;21972065;21803002);新疆维吾尔自治区自然科学基金(青年项目)(2020D01C270);伊犁师范大学科研项目(自然科学类)(2021YSYB084);污染控制及定向功能化材料设计科研团队项目(CXZK2021002)。

摘　　要：双离子电池(DIBs)基于在充电/放电过程中将阳离子和阴离子分别储存在正极和负极的工作机制,具有工作电压高、成本低和安全性出色等优点,在高效储能方面比锂离子电池更受关注。本文系统全面地综述了DIBs的基本储能原理及阴离子可逆体系理论基础,并回顾了当前DIBs最新进展。以非水系和水系双离子电池为切入点,详细介绍了DIBs正极上阴离子可逆电对设计种类,以及石墨、有机和金属层状正极材料分类及目前的研究进展。此外,还提出了一些策略和展望,希望促进DIBs未来在基础研究和产业化上的进一步发展。Dual ion battery(DIBs)is based on the working mechanism of storing cations and anions at the positive and negative electrodes,respectively,during the charging/discharging process.It has the advantages of high operating voltage,low cost and excellent safety,and has attracted more attention than lithium ion battery in the aspect of efficient energy storage.In this review,the basic energy storage principle of DIBs and the theoretical basis of anionic reversible system are systematically reviewed,and the latest progress of DIBs is included.The design types of reversible anionic pairs on DIBs positive electrode,the classification of graphite,the research progress of organic or metalbased layered positive electrode materials are introduced in detail.In addition,some strategies and prospects are put forward to promote the further development of DIBs in basic research and industrialization in the future.

关 键 词：双离子电池 正极材料 阴离子可逆体系 

分 类 号：TM912[电气工程—电力电子与电力传动]