功能性人造碱基分子的修饰及动力学研究  

MODIFICATION AND ITS DYNAMICS OF FUNCTIONAL ARTIFICIAL BASE MOLECULES

作　　者：孟庆田[1] Meng Qingtian(School of Physics and Electronics,Shandong Normal University,250358,Jinan,China)

机构地区：[1]山东师范大学物理与电子科学学院,济南250358

出　　处：《山东师范大学学报（自然科学版）》2023年第4期289-303,共15页Journal of Shandong Normal University(Natural Science)

基　　金：国家自然科学基金资助项目(12274265)。

摘　　要：概述了近些年来功能性人造碱基分子的修饰及动力学研究方面的国内外现状,并结合本团队近几年在碱基分子的修饰和功能调控研究方面所做的相关工作,在理论分析碱基分子的光电磁性质的同时,进一步阐述对人造碱基分子进行修饰的策略,探讨理论计算在功能性碱基分子设计与合成中所发挥的作用,以期能从生物物理和化学的角度为功能性分子的调控研究提供一些有意义的参考。This paper reviews some domestic and foreign research progresses in the research fields of the artificial base modification and the related dynamics in recent years.Combined with the theoretical studies on the modification and function manipulation,as well as the analysis about the optical,electrical and magnetic properties of the base molecules in these years in our group,the modification strategies of artificial bases are further elaborated,and the roles the theoretical calculation takes in the design and synthesis of functional molecules are explored.The conclusions are expected to provide a meaningful reference for the regulation research of the functional molecules from the perspective of bio⁃physics and chemistry.

关 键 词：功能性人造碱基 量子化学计算 光电磁性质 取代基和扩环修饰 

分 类 号：O56[理学—原子与分子物理] Q6[理学—物理]