以氨为燃料的管式固体氧化物燃料电池研究  

Study on Tubular Solid Oxide Fuel Cell With Ammonia as Fuel

作　　者：王振东 史彩霞 陈婷 张广君 郑国柱 王绍荣[1] Wang Zhendong;Shi Caixia;Chen Ting;Zhang Guangjun;Zheng Guozhu;Wang Shaorong(School of Chemical Engineering,China University of Mining and Technology,Jiangsu,221116;Xuzhou Puluodun Institute of Hydrogen Storage,Jiangsu,221400)

机构地区：[1]中国矿业大学化工学院,江苏221116 [2]徐州普罗顿氢能储能产业研究院,江苏221400

出　　处：《当代化工研究》2024年第3期166-168,共3页Modern Chemical Research

摘　　要：管式固体氧化物燃料电池(t-SOFC)具有易于担载催化剂、易封接等优点。本文开发了NiO-YSZ阳极支撑型t-SOFC,测试了其分别以氢气和氨气为燃料时的电化学性能。800℃,以氨气为燃料时,电池的最大功率密度略低于氢气。阻抗谱的弛豫时间分布(DRT)分析表明电池性能与氨气的分解和三相界面的离子交换有关。通过浸渍Co-Ni(3:1)纳米催化剂,800℃时氨燃料电池功率密度可提升至159.1mW/cm^(2),同时稳定性有所改善。Tubular solid oxide fuel cell(t-SOFC)has advantages of easy sealing and catalyst loading.In this paper,NiO-YSZ anode supported t-SOFC was prepared and tested with hydrogen and ammonia as fuel,respectively.At 800℃,the maximum power density of the cell fueled by ammonia is less than in hydrogen.The DRT analysis shows that the main factors affecting the cell performance are decomposition of ammonia and ion exchange at the triple phase boundary.By impregnating the Co-Ni(3:1)nanocatalyst on the anode,the power density with ammonia fuel can increase to 159.1 mW/cm^(2) at 800℃,with improved stability.

关 键 词：管式固体氧化物燃料电池 阳极支撑 氨燃料 合金催化剂 DRT分析 

分 类 号：TM911.4[电气工程—电力电子与电力传动]