5,5′-亚甲基-双-8-羟基喹啉硝基衍生物的合成与性质研究  

Synthesis and Properties of Nitro-Containing 5,5’-Methylene bis-(8-quinolinol)Derivatives

作　　者：王苒 张斌 张恒明 辛寅昌 Wan Ran;Zhang Bin;Zhang Hengming;Xin Yinchang(Shandong Yu Wang Industrial Technology Research Institute Company Limited,Jinan 250014,China;School of Chemistry,Chemical Engineering and Materials Science,Shandong Normal University,Jinan 250014,China)

机构地区：[1]山东禹王工业技术研究院有限公司,山东济南250100 [2]山东师范大学化学化工与材料科学学院,山东济南250014

出　　处：《山东化工》2023年第24期66-69,共4页Shandong Chemical Industry

摘　　要：以8羟基喹啉、甲醛为主要原料,首先制备了5,5′-亚甲基-双-8-羟基喹啉,然后经过亚硝化与硝化反应,将硝基引入到8羟基喹啉5,5′-亚甲基-双-8-羟基喹啉上,从而合成7,7'-二硝基-5,5′-亚甲基-双-8-羟基喹啉。在充分表征的基础上,对两种衍生物的各种物理和化学性质进行了深入研究。结果显示,硝基的引入对5,5′-亚甲基-双-8-羟基喹啉的各种性质产生较大的影响。5,5’-Methylene bis-(8-quinolinol)was synthesized by 8-hydroxyquinoline and formaldehyde as raw materials.Then the nitro was linked to 5,5’-Methylene bis-(8-quinolinol)by nitrosation and nitration.The derivatives were fully characterized by all the methods available and their physical and chemical properties were studied deeply.All the results show the nitro which was linked to 5,5’-Methylene bis-(8-quinolinol)has a great influence on the properties.

关 键 词：5 5′-亚甲基-双-8-羟基喹啉 亚硝化 硝化 合成 性质 

分 类 号：O633.5[理学—高分子化学]